电工技术学报  2022, Vol. 37 Issue (18): 4766-4776    DOI: 10.19595/j.cnki.1000-6753.tces.211458
高电压与放电 |
填充颗粒尺寸对介质阻挡放电降解SF6的影响
张晓星1, 周畅1, 崔兆仑2, 张国治1, 伍云健1
1.湖北工业大学新能源及电网装备安全监测湖北省工程研究中心 武汉 430068;
2.华南理工大学电力学院 广州 510640
Effect of Particle Size on Degradation of SF6 by Dielectric Barrier Discharge
Zhang Xiaoxing1, Zhou Chang1, Cui Zhaolun2, Zhang Guozhi1, Wu Yunjian1
1. Hubei Engineering Research Center for Safety Monitoring of New Energy and Power Grid Equipment Hubei University of Technology Wuhan 430068 China;
2. School of Electrical Power South China University of Technology Guangzhou 510640 China
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摘要 六氟化硫(SF6)是一种被广泛应用的优良绝缘气体,但其具有强温室效应,会对大气环境造成巨大的潜在危害。采用填充床式介质阻挡放电(DBD)降解SF6是一种有潜力的治理手段,但目前填充介质尺寸等诸多参数影响尚且未知。该文基于填充床式介质阻挡放电研究直径为1mm、2mm和4mm的γ -Al2O3颗粒对降解SF6的影响。发现小尺寸颗粒会缩减反应区域的气隙空间,使DBD体系趋于产生丝状放电;2mm填充体系的降解率及能效均优于1mm和4mm体系,主要原因可能是2mm填充颗粒兼顾较大的活性接触面积和较长的气体停留时间这两个重要因素;相比于2mm和4mm体系,1mm体系能够促进SO2气体产生,抑制SO2F2、SOF2和SOF4气体的产生。该研究结果为SF6工业无害化降解提供了理论支撑和技术指导。
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张晓星
周畅
崔兆仑
张国治
伍云健
关键词 填充颗粒尺寸介质阻挡放电放电参数降解处理SF6无害化    
Abstract:Sulfur hexafluoride (SF6) is a widely used insulating gas, but its strong greenhouse effect can cause great potential harm to the atmospheric environment. Degradation of SF6 by dielectric barrier discharge (DBD) based on packed-bed reactor is a promising treatment, but the influence of many parameters such as the size of packed medium is still unknown. In this paper, the effects of γ-Al2O3 particles with diameters of 1mm, 2mm and 4mm on the degradation of SF6 were investigated based on packed-bed type DBD. It is found that the small size of the particles will reduce the air gap space in the reaction area, so that the DBD discharge system tends to produce filamentous discharge, the degradation rate and energy efficiency of 2mm packing system are better than those of 1mm and 4mm systems, which may be attributed to the fact that the 2mm packed particles take into account the important factors of larger active contact area and longer gas residence time. Compared with 2mm and 4mm systems, the 1mm system can promote SO2 gas production and inhibit SO2F2, SOF2 and SOF4 production. The experimental results provide theoretical support and technical guidance for the industrial harmless degradation of SF6.
Key wordsPacking particle size    dielectric barrier discharge    electrical discharge parameters    degradation treatment    SF6 harmless   
收稿日期: 2021-09-13     
PACS: O539  
基金资助:湖北省自然科学基金资助项目(2020CFB166)
通讯作者: 张晓星 男,1972年生,博士,教授,博士生导师,主要研究方向为电气设备在线监测与故障诊断、状态评估、新型传感器技术、环保绝缘气体、等离子体技术。E-mail: xiaoxing.zhang@outlook.com   
作者简介: 周 畅 男,1996年生,硕士研究生,研究方向为等离子体技术。E-mail: 405793112@qq.com
引用本文:   
张晓星, 周畅, 崔兆仑, 张国治, 伍云健. 填充颗粒尺寸对介质阻挡放电降解SF6的影响[J]. 电工技术学报, 2022, 37(18): 4766-4776. Zhang Xiaoxing, Zhou Chang, Cui Zhaolun, Zhang Guozhi, Wu Yunjian. Effect of Particle Size on Degradation of SF6 by Dielectric Barrier Discharge. Transactions of China Electrotechnical Society, 2022, 37(18): 4766-4776.
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https://dgjsxb.ces-transaction.com/CN/10.19595/j.cnki.1000-6753.tces.211458          https://dgjsxb.ces-transaction.com/CN/Y2022/V37/I18/4766