Threshold Evaluation of γ Irradiation Accumulated Dose of BOPP Film Based on Trap Density
Wang Yucheng1, Li Hua1,2, Wang Zhehao1, Lin Fuchang1,2
1. State Key Laboratory of Advanced Electromagnetic Engineering and Technology Huazhong University of Science and Technology Wuhan 430074 China; 2. Key Laboratory of Pulsed Power Technology Huazhong University of Science and Technology Ministry of Education Wuhan 430074 China
Abstract:The service life of electrical systems usually depends on the endurance limit of the polymer dielectric. After irradiation, the macromolecular structure changes, and the electrical performance deteriorates, which may cause the electrical system to terminate its service life prematurely due to dielectric degradation before electrical failure. The previous studies mostly used macroscopic electrical parameters to characterize the radiation degradation of polymer films, including conductivity, dielectric loss, and breakdown strength. These parameters are easily affected by working conditions such as applied voltage and temperature. Compared with the macroscopic properties, the intrinsic microscopic properties, such as crystallization and space charge characteristics, can reflect the deterioration more accurately. In this paper, biaxially oriented polypropylene film (BOPP) as the object for capacitors was irradiated in the air. The γ irradiation dose is 0.2, 0.5, 1, 5, 10, 50, 100, 500 and 1 000 kGy. First, the surface morphology of the films before and after γ irradiation was observed. Then the heat flow curves of the films were measured by the differential scanning calorimetry (DSC) method, and the trap parameters of the films were measured by the thermally stimulated depolarization current (TSDC) method. The effects of accumulated γ irradiation dose on crystallinity, melting point, and trap parameters were studied. Finally, the threshold evaluation method of the accumulated γ irradiation dose was proposed based on the irradiation-induced trap generation model. The surface morphology observation shows that γ irradiation does not affect the shape and size of the grain on the surface of the film. The DSC test results show that the melting point and crystallinity of the films after irradiation have no significant changes when the accumulated γ irradiation dose D does not exceed 10 kGy. When D exceeds 10 kGy, the crystallinity and melting point decrease gradually with the increase of the accumulated irradiation dose. The variation of crystallinity with the accumulated irradiation dose satisfies the exponential law. When D=100 kGy, the crystallinity and melting point decreased by 7.3% and 5.7%, respectively, compared with those without irradiation. When D=1 000 kGy, the crystal region is seriously damaged, and the crystallinity and melting point are reduced by 30.7% and 15.1%, respectively, compared with those without irradiation. The TSDC test results show that the peaks of thermally stimulated depolarization current of BOPP film can be divided into three categories: the low-temperature peak whose peak temperature is near the glass transition temperature, medium-temperature peak with peak temperature lower than 90℃, high-temperature peak with peak temperature higher than 90℃. When D>10 kGy, the overall trap depth increases with the increase of D. In this paper, the trap density was taken as the characteristic quantity of film degradation, and the mathematical model of trap density Nt and accumulated γ irradiation dose D, namely, the irradiation-induced trap generation model, was established. The discrete trap density and the total trap density were used for fitting. The fitting results show that the goodness of fit of the total trap density is higher than the discrete trap density. The following conclusions can be drawn: (1) The crystallinity and melting point of BOPP film decrease with the increase of the accumulated γ irradiation dose. (2) Based on the irradiation-induced trap generation model, the coefficient ktrap of the trap density increases after irradiation was defined to characterize the degradation degree of the electrical properties of BOPP film. The total trap density was used to evaluate the threshold of accumulated γ irradiation dose to reflect the overall deterioration of the film. When D≤500 kGy, the trap density with accumulated irradiation dose satisfies the piecewise function. When ktrap≤0.25 (D≤10 kGy), the film degradation is insignificant and can be used normally. When 0.25<ktrap≤2.0 (10 kGy<D≤80 kGy), the degradation degree of the film is relatively low, and 10 kGy is taken as the initial threshold of accumulated irradiation dose for BOPP film degradation. When ktrap>2.0 (D>80 kGy), the degradation of BOPP film is severe, and 80 kGy is taken as the threshold of significant degradation.
王雨橙, 李化, 王哲豪, 林福昌. 基于陷阱密度的双向拉伸聚丙烯薄膜耐γ 辐照积累剂量阈值评估[J]. 电工技术学报, 2023, 38(18): 5039-5048.
Wang Yucheng, Li Hua, Wang Zhehao, Lin Fuchang. Threshold Evaluation of γ Irradiation Accumulated Dose of BOPP Film Based on Trap Density. Transactions of China Electrotechnical Society, 2023, 38(18): 5039-5048.
[1] 王佳昕, 李化, 王哲豪, 等. 金属化膜电容器电极边缘电场畸变研究[J]. 高压电器, 2022, 58(3): 29-36. Wang Jiaxin, Li Hua, Wang Zhehao, et al.Research on electric field distortion at the edge of metallized film capacitor electrode[J]. High Voltage Apparatus, 2022, 58(3): 29-36. [2] Laghari J R, Hammoud A N.A brief survey of radiation effects on polymer dielectrics[J]. IEEE Transactions on Nuclear Science, 1990, 37(2): 1076-1083. [3] 刘晓东, 郑晓泉, 张要强, 等. 高能电子辐照后高聚物内部空间电荷和介电性能研究[J]. 电工电能新技术, 2007, 26(1): 55-59. Liu Xiaodong, Zheng Xiaoquan, Zhang Yaoqiang, et al.Study on space charge and dielectric character of dielectric after high energy electron radiation[J]. Advanced Technology of Electrical Engineering and Energy, 2007, 26(1): 55-59. [4] 周荔丹, 闫朝鑫, 姚钢, 等. 空间辐射环境对航天器分布式电力系统关键部件的影响及应对策略[J]. 电工技术学报, 2022, 37(6): 1365-1380. Zhou Lidan, Yan Chaoxin, Yao Gang, et al.Influence of space radiation environment on critical components of spacecraft distributed power system and counter-measures[J]. Transactions of China Electrotechnical Society, 2022, 37(6): 1365-1380. [5] 于孝忠. 核辐射物理学[M]. 北京: 原子能出版社, 1981. [6] 李厚玉, 李长明, 孙伟峰. 紫外光引发聚乙烯交联技术研究进展[J]. 电工技术学报, 2020, 35(15): 3356-3367. Li Houyu, Li Changming, Sun Weifeng.Research progress in the UV-initiated polyethylene cross-linking technology[J]. Transactions of China Elec-trotechnical Society, 2020, 35(15): 3356-3367. [7] Hammoud A N, Laghari J R, Krishnakumar B.Characterization of electron-irradiated biaxially-oriented polypropylene films[J]. IEEE Transactions on Nuclear Science, 1988, 35(3): 1026-1029. [8] Hammoud A N, Laghari J R, Krishnakumar B.Effect of high energy electron radiation on MIPB-impregnated polypropylene film[J]. IEEE Transa-ctions on Nuclear Science, 1988, 35(4): 1061-1066. [9] Fisher W K, Corelli J C.Effect of ionizing radiation on the chemical composition, crystalline content and structure, and flow properties of polytetrafluoroethy-lene[J]. Journal of Polymer Science: Polymer Chemi-stry Edition, 1981, 19(10): 2465-2493. [10] McLaren K G. Dynamic mechanical studies of irradi-ation effects in polytetrafluoroethylene[J]. British Journal of Applied Physics, 1965, 16(2): 185-193. [11] Stark K H, Garton C G.Electric strength of irradiated polythene[J]. Nature, 1955, 176(4495): 1225-1226. [12] Hanks C L, Hamman D J.Radiation effects design handbook. section 3. electrical insulating materials and capacitors[R]. Washington DC, USA: NASA, 1971. [13] Hanks C L, Hamman D J.The effect of radiation on electrical insulating materials[R]. Washington DC, USA: NASA, 1969. [14] 王玉芬, 曹晓珑, 刘耀南. 聚丙烯薄膜辐射后生成电子陷阱的实验研究[J]. 西安交通大学学报, 1992, 26(2): 83-88. Wang Yufen, Cao Xiaolong, Liu Yaonan.Experi-mental investigation of electron traps induced by irradiation in polypropylene films[J]. Journal of Xi’an Jiaotong University, 1992, 26(2): 83-88. [15] Bouquet F.Responses of dielectrics to space radiation[R]. Washington DC, USA: NASA, 1986. [16] 吕恭序, 饴谷和夫, 土家满明, 等. 聚丙烯的γ 辐射效应[J]. 辐射研究与辐射工艺学报, 1988, 6(2): 17-22. Lü Gongxu, Nitani Kazuo, Tsuke Hiroaki, et al.γ irradiation effect of polypropylene[J]. Journal of Radiation Research and Radiation Processing, 1988, 6(2): 17-22. [17] 金维芳. 电介质物理学[M]. 2版. 北京: 机械工业出版社, 1997. [18] 屠德民, 王霞, 吕泽鹏, 等. 以能带理论诠释直流聚乙烯绝缘中空间电荷的形成和抑制机理[J]. 物理学报, 2012, 61(1): 409-415. Tu Demin, Wang Xia, Lü Zepeng, et al.Explanation of the formation and suppression mechanism of space charge in DC polyethylene insulation by band theory[J]. Acta Physica Sinica, 2012, 61(1): 409-415. [19] 霍金斯W L. 聚合物的稳定化[M]. 吕世光, 译. 北京: 轻工业出版社, 1981. [20] Charlesby A, Lloyd David Graham.Competitive reactions in the irradiation of anthracene+cyclohexane solutions[J]. Royal Society, 1959, 249(1256): 51-64. [21] Charlesby A, Lloyd David Graham.Radiation kinetics in anthracene-silicone mixtures[J]. Royal Society, 1960, 254(1278): 343-357. [22] 刘付德, 凌志远, 谢进, 等. 固体电介质中电致陷阱产生与电子捕获动力学[J]. 华南理工大学学报(自然科学版), 1993, 21(1): 100-107. Liu Fude, Ling Zhiyuan, Xie Jin, et al.Kinetics of trap generation and electrons capture in solid dielectrics under high electrical strength[J]. Journal of South China University of Technology (Natural Science), 1993, 21(1): 100-107. [23] 中国无损检测学会. 射线检测[M]. 北京: 机械工业出版社, 1985. [24] 梁伯润. 高分子物理学[M]. 北京: 中国纺织出版社, 2000. [25] 达督琴柯Л. К, 梅特维捷夫 С. В. 工业γ 射线探伤学[M]. 于在兹, 译. 上海: 科技卫生出版社, 1959. [26] Fujiyama M, Kawamura Y, Wakino T, et al.Study on rough-surface biaxially oriented polypropylene film. I. Formation of β-form crystals in sheet cast with T-die extruder[J]. Journal of applied polymer science, 1988, 36(5): 985-993. [27] 杨慧娴, 刘光烨, 李荣勋. 全同立构聚丙烯拉伸过程中球晶形变机理的研究进展[J]. 中国塑料, 2003, 17(6): 1-8. Yang Huixian, Liu Guangye, Li Rongxun.Research progress of the deformation mechanism for spheru-lites of isotactic polypropylene in the orientation process[J]. China Plastics, 2003, 17(6): 1-8. [28] 王力衡. 介质的热刺激理论及其应用[M]. 北京: 科学出版社, 1988. [29] Li Hua, Li Lu, Li Liwei, et al.Study on the impact of space charge on the lifetime of pulsed capacitors[J]. IEEE Transactions on Dielectrics and Electrical Insulation, 2017, 24(3): 1870-1877. [30] 李盛涛, 谢东日, 闵道敏. 聚丙烯/Al2O3纳米复合介质直流击穿特性与电荷输运仿真研究[J]. 中国电机工程学报, 2019, 39(20): 6122-6130. Li Shengtao, Xie Dongri, Min Daomin.Numerical simulation on space charge transport and DC break-down properties of polypropylene/Al2O3 nanocompo-sites[J]. Proceedings of the CSEE, 2019, 39(20): 6122-6130. [31] 王雨橙, 李化, 王哲豪, 等. 结晶度对金属化膜电容器保压性能的影响[J]. 高电压技术, 2022, 48(9): 3643-3650. Wang Yucheng, Li Hua, Wang Zhehao, et al.Voltage maintaining performance of metallized film capa-citors based on crystallinity regulation[J]. High Voltage Engineering, 2022, 48(9): 3643-3650. [32] 巫松桢, 谢大荣, 陈寿田, 等. 电气绝缘材料科学与工程[M]. 西安: 西安交通大学出版社, 1996. [33] 赵延海, 陈钢进, 张东林, 等. 聚丙烯驻极体的热刺激放电技术研究[J]. 杭州电子科技大学学报, 2013, 33(2): 73-76. Zhao Yanhai, Chen Gangjin, Zhang Donglin, et al.Study on thermally stimulated discharge technology of polypropylene electret[J]. Journal of Hangzhou Dianzi University, 2013, 33(2): 73-76. [34] 曹万强, 王勇, 李景德. 聚丙烯的动态和平衡态热刺激电流[J]. 物理化学学报, 1996, 12(12): 1090-1093. Cao Wanqiang, Wang Yong, Li Jingde.Thermally stimulated current of polypropylene in equilibrium and non-equilibrium state[J]. Acta Physico-Chimica Sinica, 1996, 12(12): 1090-1093.