Abstract：As an important part of high voltage alternating and direct current cable, semi-conductive shielding layer has the function of eliminating defects at the interfaces between cable insulation and conductor or metal shielding, thus making the interfacial electric field uniform. In this paper, the conductive mechanisms of semi-conductive shielding composites are discussed, as well as the positive/negative temperature coefficient (PTC/NTC) effects. In view of the research progress of the semi-conductive shielding layer, the influencing factors of surface smoothness of shielding layers was analyzed, and an accurate evaluation method of surface smoothness by using surface 3D profiler scanning based on white light interferometry was proposed. The effects of polymer matrix and conductive filler on the volume resistivity and the PTC effect of semi-conductive shielding composites were systematically reviewed. It is presented that a semi-conductive property at high temperature can be modified by using the combination of high aspect ratio filler and carbon black filler. Aiming at the high-voltage direct-current (HVDC) cable, the mechanism of the interface energy band structure of semi-conductive shielding layer on the space charge injection and accumulation is analyzed. Finally, the current limitations of domestic semi-conductive composites are analyzed, and the development directions of semi-conductive composites for thermoplastic environment-friendly HVDC cable is prospected.
李忠磊, 赵宇彤, 韩涛, 杜伯学. 高压电缆半导电屏蔽材料研究进展与展望[J]. 电工技术学报, 2022, 37(9): 2341-2354.
Li Zhonglei, Zhao Yutong, Han Tao, Du Boxue. Research Progress and Prospect of Semi-Conductive Shielding Composites for High-Voltage Cables. Transactions of China Electrotechnical Society, 2022, 37(9): 2341-2354.
[1] 杜伯学, 韩晨磊, 李进, 等. 高压直流电缆聚乙烯绝缘材料研究现状[J]. 电工技术学报, 2019, 34(1): 179-191. Du Boxue, Han Chenlei, Li Jin, et al.Research status of polyethylene insulation for high voltage direct current cables[J]. Transactions of China Electrotechnical Society, 2019, 34(1): 179-191. [2] 李盛涛, 王诗航, 李建英. 高压直流电缆料的研发进展与路径分析[J]. 高电压技术, 2018, 44(5): 1399-1411. Li Shengtao, Wang Shihang, Li Jianying.Research progress and path analysis of insulating materials used in HVDC cable[J]. High Voltage Engineering, 2018, 44(5): 139-1411. [3] Burns N M, Eichhorn R M.Stress controlling semiconductive shields in medium voltage power distribution cables[J]. IEEE Electrical Insulation Magazine, 1992, 8(5): 8-24. [4] 屠德民, 仇斌, 刘越, 等. 新型半导电电缆屏蔽料的工作原理[J]. 电工技术学报, 1993, 8(4): 46-51. Tu Demin, Qiu Bin, Liu Yue, Liu Ye.Principle of operation in new semiconductive material for electrical shield of power cable[J]. Transactions of China Electrotechnical Society, 1993, 8(4): 46-51. [5] 李国倡, 王家兴, 魏艳慧, 等. 高压直流电缆附件XLPE/SIR材料特性及界面电荷积聚对电场分布的影响[J]. 电工技术学报, 2021, 36(14): 3081-3089. Li Guochang, Wang Jiaxing, Wei Yanhui, et al.Effect of material properties of XLPE/SIR and interface charge accumulation on electric field distribution of HVDC cable accessory[J]. Transactions of China Electrotechnical Society, 2021, 36(14): 3081-3089. [6] IEC 62067: 2011 Power cables with extruded insulation and their accessories for rated voltages above 150 kV (Um = 170 kV) up to 500 kV (Um = 550 kV) - Test methods and requirements[S]. 2011. [7] JB/T10738—2007 额定电压35kV及以下挤包绝缘电缆用半导电屏蔽料[S]. 2007. [8] GB/T 18890.1—2015 额定电压220kV(Um=252kV)交联聚乙烯绝缘电力电缆及其附件第1部分: 试验方法和要求B/T 18890.1—2015 额定电压220kV(Um=252kV)交联聚乙烯绝缘电力电缆及其附件第1部分: 试验方法和要求[S]. 2015. [9] GB/T 11071.1—2014 额定电压110kV(Um=126kV)交联聚乙烯绝缘电力电缆及其附件第1部分: 试验方法和要求B/T 11071.1—2014 额定电压110kV(Um=126kV)交联聚乙烯绝缘电力电缆及其附件第1部分: 试验方法和要求[S]. 2014. [10] GB/T 22078.1—2008 额定电压500kV(Um=500kV)交联聚乙烯绝缘电力电缆及其附件第1部分: 额定电压500kV(Um=500kV)交联聚乙烯绝缘电力电缆及其附件—试验方法和要求[S]. 2008. [11] TICW.7.1—2012 额定电压500kV及以下直流输电用挤包绝缘电力电缆系统技术规范第1部分: 试验方法和要求[S]. 2012. [12] 杨寒. 电缆及附件用半导电材料热老化特性[D]. 哈尔滨: 哈尔滨理工大学, 2019. [13] Niu Fenying, Zhang Yewen, An Zhenlian, et al.Space charge injection in LDPE by semi-conductive electrode with different carbon black filling rates[C]// Proceedings of 2011 International Symposium on Electrical Insulating Materials, Kyoto, Japan, 2011: 12-15. [14] Xiao Chun, Zhang Yewen, An Zhenlian, et al.Interface electric field of carbon black loaded electrode and its significant influence on charge injection into polyethylene[J]. Journal of Applied Polymer Science, 2011, 123(5): 3017-3022. [15] Wei Yanhui, Han Wang, Li Ghuochang, et al.Research progress of semi-conductive shielding layer of HVDC cable[J]. High Voltage, 2020, 5(2): 1-6. [16] Lux F.Models proposed to explain the electrical conductivity of mixtures made of conductive and insulating materials[J]. Journal of Materials Science, 1993, 28(2): 285-301. [17] van Beek L K H, van Pul B I C F. Internal field emission in carbon black loaded nature rubber vulcanizates[J]. Journal of Applied Polymer Science, 1992, 24: 651-655. [18] Wang X, Nelson J, Schadler L, et al.Mechanisms leading to nonlinear electrical response of a nano p-SiC/silicone rubber composite[J]. IEEE Transactions on Dielectrics & Electrical Insulation, 2010, 17(6): 1687-1696. [19] Stepashkina A S, Tsobkallo E S, Alyoshin A N, et al.Electrical conductivity modeling and research of polypropylene composites filled with carbon black[J]. Journal of Physics Conference, 2014: 572(1), DOI: 10.1088/1742-6596/572/012032. [20] Seanor D A.Theories of electrical conductivity in polymers[C]// Conference on Electrical Insulation & Dielectric Phenomena-Annual Report 1967, Pocono Manor, PA, USA, 1967: 9-16. [21] 孙业斌, 张新民. 填充型导电高分子材料的研究进展[J]. 特种橡胶制品, 2009, 30(3): 73-77. Sun Yebin, Zhang Xinmin.Research progress of conductive filled polymer composites[J]. Special Purpose Rubber Products, 2009, 30(3): 73-77. [22] Yu Gang, Zhang Mingqiu, Zeng Hanmin, et al.Effect of filler treatment on temperature dependence of resistivity of carbon-black-filled polymer blends[J]. Applied Plymer, 1999, 73(4): 489-494. [23] Hou Yanhui, Zhang Mingqiu, Rong Minzhi, et al.Improvement of conductive network quality in carbon black‐filled polymer blends[J]. Journal of Applied Polymer Science, 2010, 84(14): 2768-2775. [24] Hou Yanhui, Zhang Mingqiu, Rong Minzhi.Performance stabilization of conductive polymer composites[J]. Journal of Applied Polymer Science, 2003, 89(9): 2438-2445. [25] Henderson A M.Ethylene-vinyl acetate (EVA) copolymers: a general review[J]. IEEE Electrical Insulation Magazine, 1993, 9(1): 30-38. [26] Zhang Fengwu.Investigating on mLLDPE/LDPE/CB composite with PTC[C]// 2013 2nd International Conference on Measurement, Information and Control (ICMIC), Harbin, 2013, DOI: 10.1109/MIC.2013. 6758205. [27] Zhang Jianfeng, Zheng Qiang, Yang Yiquan, et al.High-density polyethylene/carbon black conductive composites. I: effect of CB surface modification on its resistivity-temperature behavior[J]. Journal of Applied Polymer Science, 2010, 83: 3112-3116. [28] Jia Wentao, Chen Xinfang.PTC effect of polymer blends filled with carbon black[J]. Journal of Applied Polymer Science, 2010, 54: 1219-1221. [29] Xie Hongfeng, Deng Pengyang, Dong Lisong, et al.LDPE/carbon black conductive composites: Influence of radiation crosslinking on PTC and NTC properties[J]. Journal of Applied Polymer Science, 2010, 85(13): 2742-2749. [30] Boggs S A.500 Ω•m-low enough resistivity for a cable ground shield semicon[J]. IEEE Electrical Insulation Magazine, 2001, 17(4): 26-32. [31] Boggs S, Kuang J.High field effects in solid dielectrics[J]. IEEE Electrical Insulation Magazine, 1998, 14(6): 5-12. [32] Han S J, Mendelsohn A M, Ramachandran R.Overview of semiconductive shield technology in power distribution cables[C]// IEEE Transmission & Distribution Conference & Exhibition, Dallas, TX, USA, 2006: 641-646. [33] Nilsson U H, Bostrm J O.Influence of the semiconductive material on space charge build-up in extruded HVDC cables[C]// Conference Record of the IEEE International Symposium on Electrical Insulation, San Diego, CA, USA, 2010: 1-4. [34] Li Weikang, Zhang Chong, Zha Junwei, et al.Dispersion of carbon blacks and their influence on the properties of semiconductive materials use for high-voltage power cables[C]// 2018 IEEE International Conference on High Voltage Engineering and Application (ICHVE), Athens, Greece, 2018: 1-4. [35] Brigandi P J, Person T J, Caronia P J, et al.Impact of semiconductive shield quality on accelerated aging cable performance[C]// 2014 IEEE/PES Transmission & Distribution Conference & Exposition (T&D), Chicago, IL, USA, 2014: 1-5. [36] Belhadfa A, Houdayer A J, Hinrichsen P F, et al.Impurities in semiconductive compounds used as hv cable shields[J]. IEEE Transactions on Electrical Insulation, 1989, 24(4): 709-712. [37] Zhao Weijia, Siew W H, Given M J.The electrical performance of thermoplastic polymers when used as insulation in cables[C]// Power Engineering Conference (UPEC), 2013 48th International Universities', Dublin, Ireland, 2013, DOI:10.1109/ upec.2013.6714868. [38] Marlard T, Bezille J, Janah H, et al.Influence of migration on the electrical properties of HV extruded cables[C]// International Conference on Power Cables & Accessories 10kV-500kV, London, UK, 1993: 4576537. [39] 王威望, 李盛涛, 刘文凤. 聚合物纳米复合电介质的击穿性能[J]. 电工技术学报, 2017, 32(16): 25-36. Wang Weiwang, Li Shengtao, Liu Wenfeng.Dielectric breakdown of polymer nanocomposites[J]. Transactions of China Electrotechnical Society, 2017, 32(16): 25-36. [40] An Bo, Li Changming, Ma Fenglian, et al.Research on effect of modified semi conductive material on the space charge behaviour in XLPE[C]// International Conference on Mechatronics, 2015, 39: 2281-2287. [41] Lee K Y, Nam J C, Park D H, et al.Electrical and thermal properties of semiconductive shield for 154 kV power cable[C]//International Symposium on Electrical Insulating Materials, IEEE Computer Society, Kitakyushu, Japan, 2005, 3: 616-619. [42] 田付强, 杨春, 何丽娟, 等. 聚合物/无机纳米复合电介质介电性能及其机理最新研究进展[J]. 电工技术学报, 2011, 26(3): 1-12. Tian Fuqiang, Yang Chun, He Lijuan, et al.Recent research advancement in dielectric properties and the corresponding mechanism of polymer/inorganic nanocomposite[J]. Transactions of China Electrotechnical Society, 2011, 26(3): 1-12. [43] Wang Quan, Meng Qingguo, Wang Tinglan, et al.High-performance antistatic ethylene-vinyl acetate copolymer/high-density polyethylene composites with graphene nanoplatelets coated by polyaniline[J]. Journal of Applied Polymer Science, 2017, 134: 45303. [44] Ratzsch K F, Cecen V, Tölle F, et al.Rheology, electrical properties, and percolation of TRGO-filled EVA-copolymers[J]. Macromolecular Materials & Engineering, 2014, 299(9): 1134-1144. [45] Sumita M, Asai S, Miyadera N, et al.Electrical conductivity of carbon black filled ethylene-vinyl acetate copolymer as a function of vinyl acetate content[J]. Colloid and Polymer Science, 1986, 264(3): 212-217. [46] Yang Quanquan, Liang Jizhao.Electrical properties and morphology of carbon black-filled HDPE/EVA composites[J]. Journal of Applied Polymer Science, 2010, 117(4): 1998-2002. [47] Park J S, Kang P H, Nho Y C, et al.Effects of thermal ageing treatment and antioxidants on the positive temperature coefficient characteristics of carbon black/polyethylene conductive composites[J]. Journal of Applied Polymer Science, 2003, 89(9): 2316-2322. [48] Tang H, Liu Z Y, Piao Z H et al. Electrical behavior of carbon black-filled polymer composites: Effect of interaction between filler and matrix[J]. Journal of Applied Polymer Science, 1994, 51(7): 1159-1164. [49] 孙博阳, 陈哲, 谢傲, 等. 高碳黑含量聚丙烯电力电缆屏蔽材料[J]. 高电压技术, 2020, 46(5): 1625-1632. SUN Boyang, Chen Zhe, Xie Ao, et al.Highly filled polypropylene/carbon black shielding materials for power cables[J]. High Voltage Engineering, 2020, 46(5): 1625-1632. [50] Hou Yanhui, Zhang Mingqiu, Mai Kancheng, et al.Heat treatment-induced multiple melting behavior of carbon black-filled polymer blends in relation to the conductive performance stabilization[J]. Journal of Applied Polymer Science, 2001, 80(8): 1267-1273. [51] Luo Yanling, Wang Gengchao, Zhang Bingyu, et al.The influence of crystalline and aggregate structure on PTC characteristic of conductive polyethylene/carbon black composite[J]. European Polymer Journal, 1998, 34(8): 1221-1227. [52] Song Yihu, Zheng Qiang.Influence of annealing on conduction of high‐density polyethylene/carbon black composite[J]. Journal of Applied Polymer Science, 2007, 105(2): 710-717. [53] Miyasaka K, Watanabe K, Jojima E, et al.Electrical conductivity of carbon-polymer composites as a function of carbon content[J]. Journal of Materials Science, 1982, 17(6): 1610-1616. [54] Feng J, Chan C M.Positive and negative temperature coefficient effects of an alternating copolymer of tetrafluoroethylene-ethylene containing carbon black-filled HDPE particles[J]. Polymer, 2000, 41(19): 7279-7282. [55] Shemesh R, Siegmann A, Tchoudakov R, et al.Electrical behavior of high impact polystyrene/liquid crystalline polymer blends containing low content of carbon black[J]. Journal of Applied Polymer Science, 2006, 102(2): 1688-1696. [56] 韩宝忠, 李长明, 马凤莲. 稳恒磁场处理对聚乙烯基复合材料正温度系数特性的影响[J]. 电工技术学报, 2013, 28(2): 55-59. Han Baozhong, Li Changming, Ma Fenglian.Effect of static magnetic field treatment on positive temperature coefficient behavior of polyethyle[J]. Transactions of China Electrotechnical Society, 2013, 28(2): 55-59. [57] Moreno V M, Gorur R S.Effect of long-term corona on non-ceramic outdoor insulator housing materials[J]. IEEE Transactions on Dielectrics & Electrical Insulation, 2001, 8(1): 117-128. [58] Hirano Y, Inohara T, Toyoda M, et al.Accelerated weatherability of shed materials for composite insulators[J]. IEEE Transactions on Dielectrics & Electrical Insulation, 2001, 8(1): 97-103. [59] Zhang Hui, Hackam R.Influence of fog parameters on the aging of HTV silicone rubber[J]. IEEE Transactions on Dielectrics and Electrical Insulation, 2002, 6(6): 835-844. [60] Wang X, Yoshimura N.Fractal phenomena. Dependence of hydrophobicity on surface appearance and structural features of SIR insulators[J]. IEEE Transactions on Dielectrics and Electrical Insulation, 1999, 6(6): 781-791. [61] 朱雨涛, 谢恒堃, 金维芳, 等. 无机填料对填充型聚合物介电性能影响的研究[J]. 电工技术学报, 1996, 11(5): 11-14, 50. Zhu Yutao, Xie Hengkun, Jin Weifang, et al.A study on influence of inorganic fillers on dielectric properties of filled polymers[J]. Transactions of China Electrotechnical Society, 1996, 11(5): 11-14, 50. [62] Xu Zhongbin, Zhao Chao, Gu Aijuan, et al.Effect of morphology on the electric conductivity of binary polymer blends filled with carbon black[J]. Journal of Applied Polymer Science, 2007, 106(3): 2008-2017. [63] Cheah K, Forsyth M, Simon G P.Processing and morphological development of carbon black filled conducting blends using a binary host of poly (styrene co-acrylonitrile) and poly(styrene)[J]. Journal of Polymer Science Part B Polymer Physics, 2000, 38(23): 3106-3119. [64] Kurusu R S, Helal E, Moghimian N, et al.The role of selectively located commercial graphene nanoplatelets in the electrical properties, morphology, and stability of EVA/LLDPE blends[J]. Macromolecular Materials and Engineering, 2018, 303: 1800187. [65] Donnet J B, Voet A, Donnet J B.Carbon black: physics, chemistry, and elastomer reinforcement[M]. New York. Marcel Dekker, 1977. [66] 张晓虹, 李毓庆, 雷清泉. 改性无机填料对低密度聚乙烯电老化性能的影响[J]. 电工技术学报, 1994, 9(2): 48-52. Zhang Xiaohong, Li Yuqing, Lei Qingquan.Effect of inorganic filler on the voltage-endurance of low-density polyethylene[J]. Transactions of China Electrotechnical Society,1994, 9(2): 48-52. [67] Yang H, Yang J S, Lee K Y, et al.Thermal properties of CNT reinforced semiconductive shield materials used in power cables[C]// International Symposium on Electrical Insulating Materials (ISEIM), Yokkaichi, Japan, 2018, DOI:10.1109/ISEIM.2008.4664477. [68] George J J, Bhadra S, Bhowmick A K.Influence of carbon‐based nanofillers on the electrical and dielectric properties of ethylene vinyl acetate nanocomposites[J]. Polymer Composites, 2010, 31(2): 218-225. [69] Kalappa P, Lee J H, Rashmi B J, et al.Effect of polyaniline functionalized carbon nanotubes addition on the positive temperature coefficient behavior of carbon black/high-density polyethylene nanocomposites[J]. IEEE Transactions on Nanotechnology, 2008, 7(2): 223-228. [70] Han S J, Wasserman S H.Agglomeration and percolation network behavior of semiconductive polymer composites with carbon nanotubes[C]// IEEE International Symposium on Electrical Insulation, San Diego, CA, USA, 2010: 1-4. [71] Fang Ye, Zhao Jun, Zha Junwei, et al.Improved stability of volume resistivity in carbon black/ethylene-vinyl acetate copolymer composites by employing multi-walled carbon nanotubes as second filler[J]. Polymer, 2012, 53: 4871-4878. [72] Lee J H, Kim S K, Kim N H.Effects of the addition of multi-walled carbon nanotubes on the positive temperature coefficient characteristics of carbon-black-filled high-density polyethylene nanocomposites[J]. Scripta Materialia, 2006, 55(12): 1119-1122. [73] Lei Zhioeng, Fabiani D, Li Chuanyang, et al.Effect of graphene coating on space charge characteristic of XLPE and semiconductive layer at different temperatures[J]. IEEE Access, 2019, 7: 124540-124547. [74] Chen Weihua, Zhou Mingliang, Yan Xiaohen, et al.Study on electromagnetic-fluid-temperature multiphysics field coupling model for drum of mine cable winding truck[J]. CES Transactions on Electrical Machines and Systems, 2021, 5(2): 133-142. [75] 周凯, 李诗雨, 尹游, 等. 退运中压XLPE和EPR电缆老化特性分析[J]. 电工技术学报, 2020, 35(24): 5197-5206. Zhou Kai, Li Shiyu, Yin You, et al.Analysis of aging characteristics of medium voltage XLPE and EPR retired cables[J]. Transactions of China Electrotechnical Society, 2020, 35(24): 5197-5206. [76] 邓雯玲, 卢继平, 苟鑫, 等. 适用于高压电缆-架空线混合线路的新型重合闸方案[J]. 电力系统自动化, 2021, 45(12): 126-132. Deng Wenling, Lu Jiping, Gou Xin, et al.Novel reclosing scheme for hybird lines with high-voltage cable and overhead lines[J]. Automation of Electric Power Systems, 2021, 45(12): 126-132. [77] 孙中玉, 徐丙垠, 王玮, 等. 电缆故障脉冲电流测距系统建模与仿真[J]. 电力系统自动化, 2021, 45(4): 142-147. Sun Zhongyu, Xu Bingyin, Wang wei, et al. Modeling and simulation of cable fault location system based on pulse current[J]. Automation of Electric Power Systems, 2021, 45(4): 142-147. [78] 陈杰, 吴世林, 胡丽斌, 等. 退役高压电缆附件绝缘状态及理化性能分析[J]. 电工技术学报, 2021, 36(12): 2650-2658. Chen Jie, Wu Shilin, Hu Libin, et al.Analysis of insulation state and physicochemical property of retired high-voltage cable accessories[J]. Transactions of China Electrotechnical Society, 2021, 36(12): 2650-2658. [79] 李厚玉, 李长明, 孙伟峰. 紫外光引发聚乙烯交联技术研究进展[J]. 电工技术学报, 2020, 35(15): 3356-3367. Li Houyu, Li Changming, Sun Weifeng.Research progress in the UV-initiated polyethylene cross-linking technology[J]. Transactions of China Electrotechnical Society, 2020, 35(15): 3356-3367. [80] 尹游, 周凯, 李诗雨, 等. 基于极化去极化电流法的水树老化XLPE电缆界面极化特性分析[J]. 电工技术学报, 2020, 35(12): 2643-2651. Yin You, Zhou Kai, Li Shiyu, et al.Interface polarization characteristics of water tree aged XLPE cables based on polarization and depolarization current method[J]. Transactions of China Electrotechnical Society, 2020, 35(12): 2643-2651. [81] Lei Zhipeng, Fabiani D, Palmieri F, et al.Space charge characteristics of XLPE and semiconductive layer coated with graphene[J]. IEEE Transactions on Dielectrics and Electrical Insulation, 2020, 27(1): 128-131. [82] Lin Shisheng, Lu Yanghua, Xu Juan, et al.High performance graphene/semiconductor van der waals heterostructure optoelectronic devices[J]. Nano Energy, 2017, 40: 122-148.
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