电工技术学报  2016, Vol. 31 Issue (5): 135-143    DOI:
高电压与绝缘技术 |
微量硫化物对变压器油纸绝缘热老化特性的影响
周勇1,2,李庆民1,2,闫江燕1,2,王兆东1,2,李成榕1,2
1.华北电力大学高电压与电磁兼容北京市重点实验室 北京 102206;
2.新能源电力系统国家重点实验室(华北电力大学) 北京 102206
Impact of Trace Sulfide on the Thermal Aging Properties of the Transformer Oil-Paper Insulation
Zhou Yong1,2,Li Qingmin1,2,Yan Jiangyan1,2,Wang Zhaodong1,2,Li Chengrong1,2
1.Beijing Key Laboratory of High Voltage and Electromagnetic Compatibility North China Electric Power University Beijing 102206 China;
2.State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources North China Electric Power University Beijing 102206 China
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摘要 针对变压器出现的硫腐蚀故障,利用添加不同浓度的二苄基二硫(DBDS)或十二硫醇的变压器油、普通绝缘纸和铜片组成试品,在130 ℃下进行加速热老化实验,研究不同硫化合物对油纸绝缘系统热老化特性的影响。对实验过程定期取样,观察铜片表面颜色变化,并测量试品老化过程中绝缘纸聚合度、油中糠醛、油纸中酸值、油中微水质量分数以及油中溶解气体随老化时间的变化情况。研究结果表明,油中DBDS和十二硫醇浓度越高,绝缘纸降解速率和油中糠醛含量以及纸中酸值、油中水分的波动幅度越大,铜片腐蚀程度越严重,且铜片的腐蚀程度与氧气含量有关。添加十二硫醇的油样中,油中酸值随其浓度增大而增大;在添加DBDS的油样中,低氧时,油中酸值随DBDS浓度增大而增大,而高氧时,油中酸值随DBDS浓度增大先减小后增大。油中不同浓度的DBDS和十二硫醇对油纸绝缘系统老化产气特性表现为不同程度的促进作用。
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周勇
李庆民
闫江燕
王兆东
李成榕
关键词 油纸绝缘硫腐蚀二苄基二硫十二硫醇老化特性    
Abstract:With regards to the sulfur corrosion failure inside transformers,experimental samples,consisting of insulating oil with different concentrations of dibenzyl disulfide (DBDS) or dodecyl mercaptan,common insulating paper,and copper sheets,are used to carry out the accelerated thermal aging experiments at 130 ℃,in order to investigate the influence of different sulfur compounds on the thermal aging properties of oil-paper insulation system.During the experimental process,the color changes of the copper surface are recorded and the degree of polymerization (DP) of the insulation paper,the acid content in the paper and the water,the furfural,the acid,and the gas content in the oil are measured at regular intervals of sampling.The results indicate that the higher concentrations of DBDS and dodecyl mercaptan cause the larger fluctuation of the degradation rates of insulating paper,furfural concentration in oil,and the fluctuation ranges of paper-acid and oil-water,and furthermore bring about the more severe corrosion degree of the copper sheets,which is also related to the oxygen content dissolved in oil.In the oil samples adding dodecyl mercaptan,the oil acid rises with the increase of the dodecyl mercaptan concentration.In the oil samples adding DBDS,with the increase of the DBDS concentration,the oil acid also increases at lower oxygen content while first decreases and then increases at higher oxygen content.The different concentrations of DBDS and dodecyl mercaptan inside the oil promote different gas producing properties of the oil-paper insulation system at varying degrees.
Key wordsOil-paper insulation    sulfur corrosion    dibenzyl disulfide (DBDS)    dodecyl mercaptan    aging characteristics   
收稿日期: 2015-02-09      出版日期: 2016-03-16
PACS: TM411  
基金资助:国家自然科学基金资助项目(51477051)。
通讯作者: 李庆民,男,1968年生,教授,博士生导师,研究方向为高电压与绝缘技术、放电物理等。E-mail:lqmeee@ncepu.edu.cn     E-mail: enshizhouyong@163.com
作者简介: 周 勇 男,1988年生,硕士研究生,研究方向为油纸绝缘系统中多重硫腐蚀劣化机制。
引用本文:   
周勇,李庆民,闫江燕,王兆东,李成榕. 微量硫化物对变压器油纸绝缘热老化特性的影响[J]. 电工技术学报, 2016, 31(5): 135-143. Zhou Yong,Li Qingmin,Yan Jiangyan,Wang Zhaodong,Li Chengrong. Impact of Trace Sulfide on the Thermal Aging Properties of the Transformer Oil-Paper Insulation. Transactions of China Electrotechnical Society, 2016, 31(5): 135-143.
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