Study on Influence and Mechanismof Oil Sulfur Corrosion in Oil-Paper Insulation of Transformer Winding under the Electric Field
Yang Lijun1, Zhang Jiang1, Lu Yuncai2, Wei Chao2, Gao Sihang1
1. State Key Laboratory of Power Transmission Equipment & System Security and New Technology Chongqing University Chongqing 400044 China; 2. Electric Power Research InstituteState Grid Jiangsu Electric Power CompanyNanjing 211102 China
Abstract:In order to study the effect of corrosive sulfur in transformer oil on the performance of Oil-paper Insulation under electric field, a typical kind of corrosive sulfur-dibenzyl disulfide (DBDS) was added into the transformer insulating oil with Pig-tail winding modelunder laboratory conditions, carried out oil sulfur corrosion test under AC and DC electric field with thermal aging at 130℃for 20 days.The physicochemical properties and electrical properties of the insulating oil aged after electro-thermal impact were tested and the sulfur corrosion mechanism under the effect of electric field was studied and obtained. The results showed that the addition of AC and DC electric field could accelerate the corrosion process, and the greater the electric field intensity was, the more obvious the effect occurred. Under the AC electric field, the corrosion degree of two electrodes was similar, but under the DC electric field, the corrosion degree of two electrodes was asymmetric, which is related to the polarity of the DC high voltage power supply. It is analyzed that the copper strips of the two electrodes formed an electrolytic cell and the electrochemical corrosion occurred, copper ion released from the surface of the electrode was the main reason to accelerate the sulfur corrosion process in oil.
杨丽君, 张将, 陆云才, 蔚超, 高思航. 电场对变压器绕组油纸绝缘油硫腐蚀的影响及机理研究[J]. 电工技术学报, 2018, 33(7): 1616-1625.
Yang Lijun, Zhang Jiang, Lu Yuncai, Wei Chao, Gao Sihang. Study on Influence and Mechanismof Oil Sulfur Corrosion in Oil-Paper Insulation of Transformer Winding under the Electric Field. Transactions of China Electrotechnical Society, 2018, 33(7): 1616-1625.
[1] 廖瑞金, 郭沛, 周年荣, 等.新型抗老化混合油-纸板绝缘热老化特性[J]. 电工技术学报, 2015, 30(22): 222-230. Liao Ruijin, Guo Pei, Zhou Nianrong, et al.The thermal aging characteristics of the new anti-aging mixed oil-pressboard insulation[J]. Transactions of China Electrotechnical Society, 2015, 30(22): 222-230. [2] 国家电网公司变压器类设备专业总结报告[R]. 北京: 国家电网公司生技部,国家电网公司变压器类设备专业总结报告[R]. 北京: 国家电网公司生技部,中国电力科学研究院, 2009. [3] Tumiatti V, Maina R, Scatiggio F, et al.Corrosive sulphur in mineral oils: its detection and correlated transformer failures[C]//Electrical Insulation, Conference Record of the IEEE International Symposium, Toronto, Canada, 2006: 400-402. [4] Lipshtein R S, Shakhnovish M I.Transformer oil[M]. 2nd ed. Jerusalem: Israel Program for Scientific Translation, 1970. [5] Lance L R.Corrosive sulfur in transformer systems[J]. Chemist's Perspective, Doble Engineering Company-NETA World, Fall, 2003: 1-4. [6] Oommen T V.Corrosive and non-corrosive sulfur in transformer oils[C]//Electrical Electronics Insulation Conference and Electrical Manufacturing & Coil Winding Conference,Chicago'93 EEIC/ICWA Exposition, Chicago, America, 1993: 309-311. [7] Maina R, Tumiatti V, Pompili M, et al.Corrosive sulfur effects in transformer oils and remedial procedures[J]. IEEE Transactions on Dielectrics and Electrical Insulation, 2009, 16(6): 1655-1663. [8] 廖瑞金, 郝建, 杨丽君, 等. 变压器油纸绝缘热老化过程中铜类产物生成规律及其危害[J]. 电工技术学报, 2012, 27(10): 52-59. Liao Ruijin, Hao Jian, Yang Lijun, et al.Formation laws of copper products and their harms during transformer oil-paper insulation thermal aging process[J]. Transactions of China Electrotechnical Society, 2012, 27(10): 52-59. [9] 钱艺华, 胡红红, 姚唯建. 腐蚀性硫导致变压器故障的综合分析及处理[J]. 变压器, 2008, 45(1): 28-30. Qian Yihua, Hu Honghong, Yao Weijian.Analysis and treatment of transformer fault caused by corrosive sulfur[J]. Transformer, 2008, 45(1): 28-30. [10] 任双赞, 曹晓珑, 钟力生, 等. 变压器油中腐蚀性硫对铜导线及油浸绝缘纸特性影响[J]. 电工技术学报, 2011, 26(10): 129-135. Ren Shuangzan, Cao Xiaolong, Zhong Lisheng, et al.Influence of corrosive sulfur in transformer oil on the copper wire and oil immersed insulation paper[J]. Transactions of China Electrotechnical Society, 2011, 26(10): 129-135. [11] Holt A F, Facciotti M, Amaro P, et al.An initial study into silver corrosion in transformers following oil reclamation[C]//IEEE Electrical Insulation Conference, 2013: 469-472. [12] Kawarai H, Fujita Y, Tanimura J.Development of quantitative evaluation of copper sulfide deposition on insulating paper[C]//IEEE Conference on Electrical Insulation and Dielectric Phenomena, Quebec, Canada, 2008: 187-190. [13] Ren Shuangzan, Xu Yang, Cao Xiaolong, et al.A research summary of corrosive sulfur in mineral oils[C]//Proceedings of the 9th International Conference on Properties and Application of Dielectric Materials, Harbin,China, 2009: 353-356. [14] Amimoto T, Hosokawa N, Nagao E, et al.Concentration dependence of corrosive sulfur on copper sulfide deposition on insulating paper used for power transformer insulation[J]. IEEE Transactions on Dielectrics and Electrical Insulation, 2009, 16(5): 1489-1495. [15] Kawarai H, Fujita Y, Tanimura J, et al.Role of dissolved copper and oxygen on copper sulfide generation in insulating oil[J]. IEEE Transactions on Dielectrics and Electrical Insulation, 2009, 16(5): 1430-1435. [16] Lukic J M, Srdjan B M, Orlovic A M.Degradation of the insulating system of power transformers by copper sulfide deposition: influence of oil oxidation and presence of metal passivator[J]. Industrial & Engineering Chemistry Research, 2010, 49(20): 9600-9608. [17] Toyama S, Mizuno K.Influence of inhibitor and oil components on copper sulfide deposition on kraft paper in oil-immersed insulation[J]. IEEE Transactions on Dielectrics and Electrical Insulation, 2011, 18(6): 1877-1881. [18] Kawarai H, Uehara Y, Mizuno K, et al.Influences of oxygen and 2, 6-di-tert-butyl-p-cresol on copper sulfide deposition on insulating paper in oil-immersed transformer insulation[J]. IEEE Transactions on Dielectrics and Electrical Insulation, 2012, 19(6): 1884-1889. [19] DIN 51353-1985, testing of insulating oils; detection of corrosive sulfur; silber strip Test[S]. 1985. [20] ASTM D1275—2003, standard test method for corrosive sulfur in electrical insulation oils[S]. 2003. [21] Griffin P J, Lance L R.Understanding corrosive sulfur problems in electric apparatus[C]//Proceedings of the Seventy-fourth Annual International Conference of Doble Clients, Insulation Materials Session, Boston, MA, 2007: 1-11. [22] IEC 62535—2008, insulation liquids: test method for detection of potentially corrosive sulphur in used and unused insulating oil[S]. 2008 [23] 杨丽君, 徐积全, 胡恩德, 等. 变压器油中腐蚀性硫浓度对绕组绝缘电气性能的影响[J]. 电工技术学报, 2016, 31(10): 42-48. Yang Lijun, Xu Jiquan, Hu Ende, et al.Study on the influence of corrosive sulfur contentation in transformer oil to the electrical properties of insulated windings[J]. Transactions of China Electrotechnical Society, 2016, 31(10): 42-48. [24] 周勇, 李庆民, 闫江燕, 等. 微量硫化物对变压器油纸绝缘热老化特性的影响[J]. 电工技术学报, 2016, 31(5): 135-143. Zhou Yong, Li Qingmin, Yan Jiangyan, et al.Impact of trace sulfide on the thermal aging properties of the transformer oil-paper insulation[J]. Transactions of China Electrotechnical Society, 2016, 31(5): 135-143. [25] 王露, 曹顺安, 胡家元. 腐蚀性硫导致变压器故障的原因及其影响因素研究[J]. 变压器, 2011, 48(5): 45-48. Wang Lu, Cao Shun’an, Hu Jiayuan.The study of corrosive sulfurcauses and influencing factors of transformer fault[J]. Transformer, 2011, 48(5): 45-48. [26] Amaro P S, Holt A F, Facciotti M, et al.Impact of corrosive sulfur in transformer insulation paper[C]//Electrical Insulation Conference, Ottawa, Ontario, Canada, 2013: 459-463. [27] Bolliger D, Pilania G, Boggs S.The effect of aromatic and sulfur compounds on partial discharge characteristicsof hexadecane[J]. IEEE Transactions on Dielectrics and Electrical Insulation, 2013, 20(3): 801-813. [28] Kato F, Amimoto T, Nagao E, et al.Effect of DBDS concentration and heating duration on copper sulfide formation in oil-immersed transformer insulation[J]. IEEE Transactions on Dielectrics and Electrical Insulation, 2011, 18(6): 1869-1876. [29] GB/T 1410—2006材料体积电阻率和表面电阻率试验方法[S]. 2006. [30] Maina R, Tumiatti V, Pompili M, et al.Dielectric loss characteristics of copper contaminated transformer oils[J]. IEEE Transactions on Power Delivery, 2010, 25(3): 1673-1677.