电工技术学报  2020, Vol. 35 Issue (zk1): 311-319    DOI: 10.19595/j.cnki.1000-6753.tces.L80364
高电压与绝缘 |
Me-THPA扩链改性环氧树脂对其固化物绝缘特性的影响
赵玉顺, 何元菡, 杨克荣, 王学培, 张松
合肥工业大学电气与自动化工程学院 合肥 230009
Insulation Performance of Me-THPA Chain-Extended Epoxy Resin Cured Products
Zhao Yushun, He Yuanhan, Yang Kerong, Wang Xuepei, Zhang Song
School of Electrical and Automation Engineering Hefei University of Technology Hefei 230009 China
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摘要 盆式绝缘子是气体绝缘开关设备(GIS)中的关键部件,运行中的盆式绝缘子发生过多次表面闪络事故,影响电网安全运行。盆式绝缘子的绝缘性能取决于环氧树脂/Al2O3复合材料的综合性能,该文使用甲基四氢邻苯二甲酸酐(Me-THPA)对低分子量环氧树脂进行扩链改性,探究了扩链后环氧树脂的分子量分布和固化特性。在此基础上,制备了扩链树脂/Al2O3复合绝缘材料,试验研究了这种材料固化产物的体击穿特性和沿面闪络特性。研究结果表明,采用Me-THPA达到了对环氧树脂扩链改性的目的,降低了环氧树脂的树脂固化放热速率,且扩链环氧树脂/Al2O3固化物的体击穿强度和沿面闪络电压都有一定程度提升,研究结果可为盆式绝缘子绝缘能力的提高提供参考。
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赵玉顺
何元菡
杨克荣
王学培
张松
关键词 环氧树脂复合绝缘材料扩链改性固化特性击穿特性沿面闪络特性    
Abstract:The basin-type insulators are key component in the gas insulated switchgear (GIS). However, many surface flashover accidents occurred during the operation of the basin-type insulators, threaten the safe operation of power grid. The insulation performance of the basin-type insulators depend on the properties of the castable epoxy resin (EP) composite materials. In this paper, methyl tetrahydrophthalic anhydride (Me-THPA) was used to extend the molecular chain of low molecular weight epoxy resin, the molecular weight distribution and curing characteristics of the chain-extended epoxy resin were investigated. On the basis, the chain-extended epoxy resin/Al2O3 composite materials were prepared, and the breakdown characteristics and surface flashover characteristics of the composite material cured products were tested. The results showed that Me-THPA had achieved the purpose of chain extension of the low molecular weight epoxy resin, the heat release during curing of the chain-extended epoxy resins was reduced. In addition, the breakdown voltage and the surface flashover voltage of chain-extended epoxy resin/Al2O3 cured products had improved. It was hoped that the research results could provide reference for the improvement of the insulation capability of the basin-type insulators.
Key wordsEpoxy resin composite materials    chain extension    curing characteristics    breakdown characteristics    surface flashover characteristics   
收稿日期: 2018-06-30      出版日期: 2020-03-05
PACS: TM216+3  
基金资助:国家重点研发计划“特高压电气设备用纳米复合绝缘材料与应用关键技术”重点专项(2017YFB0903800)资助
通讯作者: 赵玉顺 男,1980年生,博士,副教授,硕士生导师,研究方向为高电压与绝缘技术、电力设备在线监测与故障诊断和雷电防护等。E-mail: yushunzhao@126.com   
作者简介: 何元菡 女,1995年生,硕士研究生,研究方向为高电压与绝缘技术。E-mail: 929238569@qq.com
引用本文:   
赵玉顺, 何元菡, 杨克荣, 王学培, 张松. Me-THPA扩链改性环氧树脂对其固化物绝缘特性的影响[J]. 电工技术学报, 2020, 35(zk1): 311-319. Zhao Yushun, He Yuanhan, Yang Kerong, Wang Xuepei, Zhang Song. Insulation Performance of Me-THPA Chain-Extended Epoxy Resin Cured Products. Transactions of China Electrotechnical Society, 2020, 35(zk1): 311-319.
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https://dgjsxb.ces-transaction.com/CN/10.19595/j.cnki.1000-6753.tces.L80364          https://dgjsxb.ces-transaction.com/CN/Y2020/V35/Izk1/311