Comparison of Discharge Characteristics of Atmospheric Pressure Plasma Jet in Ar/O2 and Ar/H2O Mixtures
Zhou Yixiao1,2,Fang Zhi1,Shao Tao2,3
1. Nanjing University of Technology Nanjing 210009 China 2. Institute of Electrical Engineering,Chinese Academy of Sciences Beijing 100190 China 3. Key Laboratory of Power Electronics and Electric Drive Chinese Academy of Sciences Beijing 100190 China
Abstract:In order to compare characteristics of atmospheric pressure jet(APPJ) plasmas produced in Ar/O2 mixtures and Ar/H2O mixtures with the same contents of oxygen and water vapor,the effects of Ar/O2 and Ar/H2O mixtures on discharge characteristics and evolutions of APPJ are studied by means of voltage and current waveforms,Lissajous figures,light-emission pictures,and optical emission spectra. The main discharge parameters such as discharge power,transported charges,electronic excitation temperature,molecular vibrational temperature,and molecular rotational temperature are calculated. The changing tendencies of these parameters with applied voltage are studied,and the experimental results are explained. Results show that two kinds of APPJs include three stages: corona discharge,dielectric barrier discharge and jet discharge formation. For two kinds of APPJs,the jet length increases with the increase of applied voltage. The APPJs in Ar/O2 and Ar/H2O plasmas are a typical non-thermal one with gas temperature in the range of 300~650K,in which the main species are OH,N2,Ar and a little O. In the range of 7~9.5kV,Ar/H2O plasma jet spectral intensity is higher than that of Ar/O2. Through the electronic excitation temperature and molecular rotation temperature calculation,it can be found that the electronic temperature difference under the conditions of argon oxygen and argon water is weak,but gas temperature is lower in case of argon water,which indicates that Ar/H2O plasma jet is better for surface treatment of heat sensitive material.
[1] 章程,邵涛,于洋,等. 纳秒脉冲介质阻挡放电特性及其聚合物材料表面改性[J]. 电工技术学报,2010,25(05): 31-37. Zhang Cheng,Shao Tao,Yu Yang,et al. Characteristics of unipolar nanosecond pulse DBD and its application on surface treatment of polyimer films[J]. Transactions of China Electrotechnical Society,2010,25(5): 31-37. [2] 章程,邵涛,龙凯华,等. 大气压空气中纳秒脉冲介质阻挡放电均匀性的研究[J]. 电工技术学报,2010,25(01): 30-36. Zhang Cheng,Shao Tao,Long Kaihua,et al. Uniform of unipolar nanosecond pulse DBD in atmospheric air[J]. Transactions of China Electrotechnical Society,2010,25(01): 30-36. [3] 方志,蔡玲玲. 空气中均匀介质阻挡放电功率密度对聚四氟乙烯表面改性的影响[J]. 高电压技术,2011,37(6): 1459-1464. Fang Zhi,Cai Lingling. Effects of power density on surface modification of polytetra fluorethylene by using a homogeneous dielectric barrier discharge at atmospheric air[J]. High Voltage Engineering,2011,37(6): 1459- 1464. [4] 郝艳捧,王晓蕾,阳林. 大气压氦气介质阻挡放电多脉冲辉光放电的形成条件[J]. 电工技术学报,2009,24(09): 29-32. Hao Yanpeng,Wang Xiaolei,Yang Lin. Formation of dielectric barrier multi-pulse glow discharges in helium at atmospheric pressure[J]. Transactions of China Electrotechnical Society,2009,24(9): 28-32. [5] 牛铮,邵涛,章程,等. 纳秒脉冲放电等离子体射流特性[J]. 强激光与粒子束,2012,24(3): 617-620. Niu Zheng,Shao Tao,Zhang Cheng,et al. Charac- teristics of nanosecond-pulse atmospheric pressure plasma jet[J]. High Power Laser and Particle Beams,2012,24(3): 617-620. [6] Kuwabara A,Kuroda S,Kubota H. Development of atmospheric pressure low temperature surface discharge plasma torch and application to polypropylene surface treatment[J]. Plasma Chemistry and Plasma Processing,2008,28(2): 263-271. [7] Seo Y S,Mohamed A A H,Woo K C,et al. Comparative studies of atmospheric pressure plasma characteristics between He and Ar working gases for sterilization[J]. IEEE Transactions on Plasma Science,2010,38(10): 2954-2962. [8] Niu Z,Shao T,Zhang C,et al. Atmoshperic-pressure plasma jet produced by a unipolar nanosecond pulse generator in various gases[J]. IEEE Transactions on Plasma Science,2011,39(11): 2322-2323. [9] Li X M,Qiu Y P. The application of He/O 2 atmospheric pressure plasma jet and ultrasound in desizing of blended size on cotton fabrics[J]. Applied Surface Science,2012,258(19): 7787-7793. [10] Sarani A,Geyter N D,Nikiforov A Y,et al. Surface modification of PTFE using an atmospheric pressure plasma jet in argon and argon+CO 2 [J]. Surface & Coatings Technology,2012,206(8-9): 2226-2232. [11] Haslinger S,Laimer J,Stori H. Stability conditions of argon and helium gas mixtures in an atmospheric pressure plasma jet[J]. Vacuum,2007,82(2): 142-145. [12] Kim D B,Gweon B,Moon S Y,et al. Surface treatment comparison using atmospheric helium plasma jets with different frequencies and target objects[J]. Thin Solid Films,2010,518(22): 6700-6703. [13] Deng S X,Cheng C,Ni G H,et al. The interaction of an atmospheric pressure plasma jet using argon or argon plus hydrogen peroxide vapour addition with bacillus subtilis[J]. Chinese Physics,2010,19(10): 105203(1-6). [14] 刘丹,张海鸥,王桂兰. 氩氮气体混合比对等立体射流温度和涂层特性的影响[J]. 材料工程,2003,11(4): 45-48. Liu Dan,Zhang Hai’ou,Wang Guilan,Effect of the Ar-N 2 mixture ratios on temperature of the plasma jet and properties of the coating[J]. Journal of Materials Engineering,2003,11(4): 45-48. [15] 于洋,邵涛,章程,等. 单极性纳秒脉冲介质阻挡放电电荷传输特性实验分析[J]. 高电压技术,2011,37(6): 1555-1562. Yu Yang,Shao Tao,Zhang Cheng,et al. Experimental analysis on charges transported in dielectric barrier discharge using unipolar nanosecond-pulse generator[J]. High Voltage Engineering,37(6): 1555-1562. [16] Fang Z,Cai L L,Lei X,et al. Surface Treatment of polypropylene films using homogeneous DBD plasma at atmospheric pressure in air[J]. High Voltage Engineering,2011,37(11): 2746-2751. [17] Lerous F,Campagne C,Perwuelz A,et al. Poly- propylene film chemical and physical modifications by dielectric barrier discharge plasma treatment at atmospheric pressure[J]. Journal of Colloid and Interface Science,2008,328(2) : 412-420. [18] 严建华,潘新潮,马增益,等. 直流氩等离子体射流电子温度的测量[J]. 光谱学与光谱分析,2008,28(1): 6-9. Yan Jianhua,Pan Xinchao,Ma Zengyi,et al. Temperature measurement of DC argon plasma jet[J]. Spectroscopy and Spectral Analysis,28(1): 6-9. [19] 刘源,方志,蔡玲玲. 增强聚丙烯薄膜表面经大气压氩等离子体射流改性后的亲水性[J]. 高电压技术,,2012,38(5): 1141-1149. Liu Yuan,Fang Zhi,Cai Lingling. Improving hydro- philictiy of polypropylene film using atmospheric pressure plasma jet in argon[J]. High Voltage Enginee- ring,38(5): 1141-1149. [20] Shao X J,Zhang G J,Zhan J Y,et al. Research on surface modification of polytetrafluoroethylene coupled with argon dielectric barrier discharge plasma jet characteristics[J]. IEEE Transactions on Plasma Science,2011,39(11): 3095-3102. [21] Ralchenko Y,Kramida A,Reader J,et al. Nist atomic spectra database[DB/OL]. [2011-12-16]. 2012,http: //www.nist.gov/pml/data/asd.cfm. [22] 张连水,程学良,党伟,等. 氮分子对激发态氩原子的淬灭效应[J]. 河北大学学报(自然科学版),2011,31(5): 469-474. Zhang Lianshui,Cheng Xueliang,Dang Wei,et al. Quenching effect of nitrgen molecule to argon atom in excited state[J]. Journal of Hebei University (Natural Science Edition),2011,31(5): 469-474. [23] 李雪辰,袁宁,贾鹏英,等. 发射光谱研究大气压等离子体射流的气体温度[J]. 光谱学与光谱分析,2011,30(11): 2894-2896. Li Xuechen,Yuan Ning,Jia Pengying,et al. Investiga- tion on the gas temperature of a plasma jet at atmos- pheric pressure by emission spectrum[J]. Spectroscopy and Spectral Analysis,30(11): 2894-2896. [24] 刘忠伟,陈强,王正铎,等. 大气压射流等离子体及OH自由基的发射光谱在线诊断[J]. 强激光与粒子束,2010,22(10): 2461-2464. Liu Zhongwei,Chen Qiang,Wang Zhengduo,et al. On-line diagnosis of O and OH radical in atmospheric pressure plasma jet by optical emission spectroscopy [J]. High Power Laser And Particle Beams,2010,22(10): 2461-2464. [25] Qian M Y,Ren C S,Wang D Z,et al. Investigation on an atmospheric dielectric barrier discharge plasma jet with a concentric wire-mesh cylinder electrode con- figuration[J]. IEEE Transactions on Plasma Science,2012,40(4): 1134-1141. [26] Wei G D,Ren C S,Qian M Y,et al. Optical and electrical diagnostics of cold Ar atmospheric pressure plasma jet generated with a simple DBD configura- tion[J]. IEEE Transactions on Plasma Science,2011,39(9): 1842-1848. [27] 冉俊霞,毛志国,董丽芳. 大气压氩气介质阻挡放电光谱[J]. 河北大学学报,2004,24(5): 468-488. Ran Junxia,Mao Zhiguo,Dong Lifang,et al. Spectrum of argon dielectric barrier discharge at a atmospheric pressure[J]. Journal of Hebei University (Natural Science Edition),2004,24(5): 486-488.