Abstract:In recent years, polyolefin composite insulators have played a very significant role in the prevention and control of bird damage, but the hydrophobicity of polyolefin materials has been rarely studied. In this paper, the hydrophobic character of polyolefin material and silicone rubber was evaluated by the static contact angle and spray method. The hydrophobicity nominal, reduction and recovery property of the two materials were comparability studied according to the static contact angle (θs) and hydrophobicity class. And the hydrophobicity of the two materials in three characteristic stages was analyzed by the microstructure and surface roughness. Further, the hydrophobicity transfer property of polyolefin materials which were contaminated with an artificial pollution slurry and a dry diatomite had been studied. The results show that nonpolar polyolefin material has good hydrophobicity. Due to the small surface roughness, the static contact angle of polyolefin materials is lower, but is still above the minimum required values as per China national standard GB/T 19519—2014. The continuous and uniform pollution layer can not be formed on the surface of the polyolefin material by conventional pasting method. However, with the increasing of transfer time, the static contact angle of polyolefin material which is covered with dry diatomite increases continuously, and the variation of the static contact angle is tending towards stability after transfer for 78h. It is clear from the results that the polyolefin material has hydrophobicity transfer property to dry diatomite.
彭静, 刘云蔚, 危鹏, 刘志强, 张长征. 硬质复合绝缘子用伞套材料憎水性研究[J]. 电工技术学报, 2021, 36(zk1): 14-21.
Peng Jing, Liu Yunwei, Wei Peng, Liu Zhiqiang, Zhang Changzheng. Research on Hydrophobicity of Polyolefin Materials for the Hard Shed of Composite Insulators. Transactions of China Electrotechnical Society, 2021, 36(zk1): 14-21.
[1] Tokoro T, Inoki T, Wada E, et al.Diagnosis of degradation condition of silicone rubber using hydrophobic surface analysis[C]//2008 International Symposium on Electrical Insulating Materials, Yokkaichi, Japan, 2008: 445-448. [2] 张志劲, 张翼, 蒋兴良, 等. 自然环境不同年限复合绝缘子硅橡胶材料老化特性表征方法研究[J]. 电工技术学报, 2020, 35(6): 1368-1376. Zhang Zhijin, Zhang Yi, Jiang Xingliang, et al.Study on aging characterization methods of composite insulators aging in natural environment for different years[J]. Transactions of China Electrotechnical Society, 2020, 35(6): 1368-1376. [3] 梁英, 高婷, 王祥念, 等. 电场和温度协同作用下复合绝缘子用硅橡胶微观结构演化[J]. 电工技术学报, 2020, 35(7): 193-201. Liang Ying, Gao Ting, Wang Xiangnian, et al.Microstructure evolution of silicone rubber used for composite insulators under the effects of electric field and temperature[J]. Transactions of China Electro- technical Society, 2020, 35(7): 193-201. [4] Yang Zhaoxiang, Jia Zhidong, Chen Can, et al.Hydrophobicity distribution analysis of DC com- posite insulators[C]//2014 IEEE Electrical Insulation Conference, Philadelphia, PA, USA, 2014: 465-468. [5] 张锐, 吴光亚. 500kV交、直流输电线路鸟啄损坏复合绝缘子统计和分析[J]. 电瓷避雷器, 2005(5): 11-14. Zhang Rui, Wu Guangya.Statistic and analysis on bird damage to 500kV AC and DC transmission line composite insulators[J]. Insulators and Surge Arresters, 2005(5): 11-14. [6] 彭静, 井谦, 何远华, 等. 聚烯烃复合绝缘子伞套材料性能试验及分析[J]. 电瓷避雷器, 2020(2): 244-249. Peng Jing, Jing Qian, He Yuanhua, et al.Experiment and analysis of housing material for polyolefin composite insulator[J]. Insulators and Surge Arresters, 2020(2): 244-249. [7] 胡文歧, 井谦, 彭静. 接触角法表征复合绝缘子用硅橡胶材料表面憎水性的研究[J]. 电瓷避雷器, 2013(2): 5-10. Hu Wenqi, Jing Qian, Peng Jing.Study on surface hydrophobicity of silicone rubber materials for composite insulator characterized by contact angle method[J]. Insulators and Surge Arresters, 2013(2): 5-10. [8] 夏云峰, 宋新明, 何建宗, 等. 复合绝缘子用硅橡胶老化状态评估方法[J]. 电工技术学报, 2019, 34(增刊1): 440-448. Xia Yunfeng, Song Xinming, He Jianzong, et al.Evaluation method of aging for silicone rubber of composite insulator[J]. Transactions of China Elec- trotechnical Society, 2019, 34(S1): 440-448. [9] 标称电压高于1000V交流系统用悬垂和耐张复合绝缘子定义、试验方法及接收准则:GB/T 19519— 2014[S]. 2014. [10] 绝缘子表面湿润性测量导则:GB/T 24622—2009[S]. 2010. [11] ±500kV及以上电压等级直流棒形悬式复合绝缘子技术条件:DL/T 810—2012[S]. 2012. [12] 姚继莎. 自然环境中复合绝缘子憎水性变化特性及机理的研究[D]. 北京: 华北电力大学, 2006. [13] 李汉堂. 绝缘子用硅橡胶[J]. 世界橡胶工业, 2006, 33(6): 6-8. Liu Hantang.Silicone rubber for insulators[J]. World Rubber Industry, 2006, 33(6): 6-8. [14] 赵翮选, 赵书荣, 王联章, 等. 高海拔地区紫外辐射对硅橡胶复合绝缘子老化的影响[J]. 华北电力技术, 2009(3): 10-13. Zhao Hexuan, Zhao Shurong, Wang Lianzhang, et al.Influence of UV-irradiation on degradation of silicone rubber composite insulators in high-altitude regions[J]. North China Electric Power, 2009(3): 10-13. [15] 程帅, 董云开, 张向军. 规则粗糙固体表面液体浸润性对表观接触角影响的研究[J]. 机械科学与技术, 2007, 26(7): 822-827. Cheng Shuai, Dong Yunkai, Zhang Xiangjun.Study of the influence of apparent contact angle on regular rough surface considering liquid wetting properties[J]. Mechanical Science and Technology for Aerospace Engineering, 2007, 26(7): 822-827. [16] Barthlott W, Neinhuis C.Purity of the sacred lotus, or escape from contamination in biological surfaces[J]. Planta, 1997, 202(1): 1-8. [17] 杨洪达, 李卫国, 黄晓义, 等. 不同配方硅橡胶憎水性恢复与迁移特性[J]. 科学技术与工程, 2019, 19(9): 94-98. Yang Hongda, Li Weiguo, Huang Xiaoyi, et a1. Hydrophobic recovery and migration characteristics of different formulations of silicone rubber[J]. Science Technology and Engineering, 2019, 19(9): 94-98. [18] Shi Jia, Dong Hao, Quan Yiwu, et al.Evaluation of thermoplastic polyolefin materials for the hard shed of composite insulators[J]. Journal of Applied Poly- mer Science, 2020, 137(36): 49080. [19] 戴罕奇, 梅红伟, 王黎明, 等. 复合绝缘子弱憎水性状态描述方法Ⅰ——静态接触角法的适用性[J]. 电工技术学报, 2013, 28(8): 34-47. Dai Hanqi, Mei Hongwei, Wang Liming, et al.Description method I for unobvious hydrophobic state of composite insulators-usability of contact angle method[J]. Transactions of China Electro- technical Society, 2013, 28(8): 34-47. [20] 戴罕奇, 梅红伟, 王黎明, 等. 复合绝缘子弱憎水性状态描述方法Ⅱ——喷水分级法的不确定性[J]. 电工技术学报, 2015, 30(3): 240-249. Dai Hanqi, Mei Hongwei, Wang Liming, et al.Description method Ⅱ for unobvious hydrophobic state of composite insulators-uncertainty of hydrophobic degree by spray grading method[J]. Transactions of China Electrotechnical Society, 2015, 30(3): 240-249. [21] 陶维亮, 王先培, 刘艳, 等. 复合绝缘子接触角的图像处理检测[J]. 电机与控制学报, 2009, 13(2): 232-237, 244. Tao Wei1iang, Wang Xianpei, Liu Yan, et al. Mea- surement on composite insulators’ contact angles based on image processing[J]. Electric Machines and Control, 2009, 13(2): 232-237, 244. [22] Basanta G K, Shigeki M, Kenji S.Effect of core diameter of cylindrical polymer insulators on con- tamination flashover voltage-part I[J]. IEEJ Transa- ctions on Electrical and Electronic Engineering, 2006, 1(3): 298-305. [23] 赵新泽, 鲜于文玲, 赵美云, 等. 复合绝缘子伞裙表面粗糙度对其憎水性影响研究[J]. 三峡大学学报(自然科学版), 2016, 38(1): 85-88. Zhao Xinze, Xianyu Wenling, Zhao Meiyun, et a1. Study of effect of umbrella skirt surface roughness on hydrophobicity of composite insulator[J]. Journal of China Three Gorges University (Natural Sciences), 2016, 38(1): 85-88.