电工技术学报  2018, Vol. 33 Issue (21): 5136-5142    DOI: 10.19595/j.cnki.1000-6753.tces.171683
高电压与绝缘 |
噻吩对变压器油纸绝缘系统热老化特性研究
丛浩熹, 舒想, 张敏昊, 李庆民
华北电力大学电气与电子工程学院 北京 102206
Influence of Thiophene on Thermal Aging of the Transformer Oil-Paper Insulation System
Cong Haoxi, Shu Xiang, Zhang Minhao, Li Qingmin
School of Electrical and Electronic Engineering North China Electric Power University Beijing 102206 China
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摘要 为研究噻吩对变压器油纸绝缘系统热老化的影响规律,将添加总硫的质量浓度相等的苯并噻吩(BT)与二苄基二硫(DBDS)的油样在140℃温度下进行加速热老化试验,定期取样测试相应老化特征参量。研究结果表明:噻吩比较稳定,一般情况下不与铜片发生反应,对高温氧气环境也有一定的耐受能力,但长期处于高温高氧环境下可能转变成某种具有腐蚀性的硫化物;噻吩能够减小油中糠醛含量、油中水分及纸中水分的波动幅度、绝缘纸聚合度的下降速率,使油中酸值拐点延后,能在一定程度上延缓油纸绝缘系统的老化,是一种天然的抗氧化剂。综合来看,噻吩对于延缓油纸绝缘系统的老化具有一定的积极作用,但仍需要控制变压器运行过程中油中氧气含量及变压器的运行温度,防止长期高温高氧环境的存在,从而预防硫腐蚀故障的发生。
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关键词 变压器噻吩腐蚀性硫油纸绝缘热老化    
Abstract:In order to study the influence of thiophene on the thermal aging of transformer oil paper insulation system, the BT and DBDS with the same content of sulfur were compared. The accelerated thermal aging test was carried out at 140℃. The aging characteristic parameters were measured during the aging process. The results show that the thiophene is relatively stable, and it will not react with the copper in general. It can also have some tolerance in the high temperature and high oxygen environment in a short period. However, in the long-term high temperature and high oxygen environment, it may convert to some kind of corrosive sulfide which could react with copper. The amount of furfural and the moisture content in the oil, the fluctuation range of the moisture in the paper and the decrease rate of the polymerization degree in the insulating paper are reduced, and the acid value of the oil is delayed. It can have a positive effect to delay the aging of oil-paper insulation system, which means a natural antioxidant. Taken together, the thiophene can delay the aging of oil-paper insulation system. However, it needs to control the oxygen content in oil and the operating temperature of transformer during the operation of transformer, especially to avoid the long-term high temperature and high oxygen environment in order to prevent the occurrence of sulfur corrosion failure.
Key wordsTransformer    thiophene    corrosive sulfur    oil-paper insulation    thermal aging   
收稿日期: 2017-12-12      出版日期: 2018-11-12
PACS: TM855  
基金资助:国家自然科学基金资助项目(51477051和51628701)
作者简介: 丛浩熹 男,1989年生,博士,讲师,研究方向为电力设备在线监测与故障诊断、气体放电与等离子体。E-mail:conghaoxi@ncepu.edu.cn(通信作者);舒 想 男,1994年生,硕士研究生,研究方向为变压器油中腐蚀性硫。E-mail:765348794@qq.com
引用本文:   
丛浩熹, 舒想, 张敏昊, 李庆民. 噻吩对变压器油纸绝缘系统热老化特性研究[J]. 电工技术学报, 2018, 33(21): 5136-5142. Cong Haoxi, Shu Xiang, Zhang Minhao, Li Qingmin. Influence of Thiophene on Thermal Aging of the Transformer Oil-Paper Insulation System. Transactions of China Electrotechnical Society, 2018, 33(21): 5136-5142.
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