Abstract:Photoacoustic spectroscopy (PAS) is a new method to detect the trace gas dissolved in the transformer oil.It utilizes the measurement of the electromagnetic energy absorbed by the transformer oil by means of acoustic detection.The PAS is characterized by high sensitivity,wide detective range,good selectivity and maintenance free.In this paper,the principle of PAS used for dissolved gas detection in transformer oil has been introduced first.Then the absorption spectral has been analyzed qualitatively and quantitatively.A dissolved gas detection system consisting of a dynamic headspace degasses and the trace gas meter with PAS has been built.Field test has also been conducted and the improvements have been made considering the effect of internal noise,environmental temperature and humidity.Experimental results demonstrate the accuracy of trace gas detection is well with the national and IEC standards.
毛知新, 文劲宇. 变压器油中溶解气体光声光谱检测技术研究[J]. 电工技术学报, 2015, 30(7): 135-143.
Mao Zhixin, Wen Jinyu. Research on the Detection of the Dissolved Gas in the Transformer Oil by Photoacoustic Spectroscopy. Transactions of China Electrotechnical Society, 2015, 30(7): 135-143.
[1] Rosencwig A.Photoacoustics and Photoacoustic spectroscopy[M].John Wiley & Sons Inc.,New York:1980. [2] 李洋流,赵学增.基于光声光谱的变压器油中溶解气体监测系统[J].传感器与微系统,2011,30(6):103-105. Li Yangliu,Zhao Xuezeng.Monitoring system for dissolved gases in transformer oil based on Photoacoustic Spectroscopy[J].Transducer and Microsystem Technologies,2011,30(6):103-105. [3] 陈伟根,云玉新,潘翀,等.光声光谱技术应用于变压器油中溶解气体分析[J].电力系统自动化,2007,31(15):94-98. Chen Weigen,Yun Yuxin,Pan Chong,et al.Gas-in-oil Analysis in transformers based on Photoacoustic Spectrometry[J].Automation of Electric Power Systems,2007,31(15):94-98. [4] 赵笑笑,云玉新,陈伟根.变压器油中溶解气体的在线监测技术评述[J].电力系统保护与控制,2009,37(23):187-191. Zhao Xiaoxiao,Yun Yuxin,Chen Weigen.Comment on on-line monitoring techniques for dissolved gas in transformer oil[J].Power System Protection and Control,2009,37(23):187-191. [5] Wan F,Chen W G,Peng X J,et al.Study on the gas pressure characteristics of photoacoustic spectroscopy detection for dissolved gases in transformer oil[C].2012 International Conference on High Voltage Engineering and Application (ICHVE),Shanghai,China,2012:286-289. [6] Abu Bakar N,Abu-Siada A,Islam S.A review of dissolved gas analysis measurement and interpretation techniques[J].IEEE Electrical Insulation Magazine,2014,30(3):39-49. [7] Pao Yoh-Han.Optoacoustic Spectroscopy and Detection[M].Academic Press,New York:1977. [8] Michaelian K H.Invited article:linearization and signal recovery in photoacoustic infrared spectroscopy[J].Review of Scientific Instruments,2007,78(5):1-12. [9] Skelly D.Photo-Acoustic spectroscopy for dissolved gas analysis benefits and experience[C].Proceedings of 2012 IEEE International Conference on Condition Monitoring and Diagnosis,Bali,Indonesia,2012:39-43. [10]刘先勇,周方洁,胡劲松,等.光声光谱在油中气体分析中的应用前景[J].变压器,2004,41(7):30-33. Liu Xianyong,Zhou Fangjie,Hu Jinsong,et al.Prospect to apply photoacoustic spectroscopy in dissolved gasses in oil analysis[J].Transformer,2004,41(7):30-33. [11]云玉新,陈伟根,孙才新,等.变压器油中甲烷气体的光声光谱检测方法[J].中国电机工程学报,2008,28(34):40-46. Yun Yuxin,Chen Weigen,Sun Caixin,et al.Photoacoustic detection of methane dissolved in transformer oil[J].Proceedings of the CSEE,2008,28(34):40-46. [12]张镱议,廖瑞金,杨丽君,等.基于云理论的电力变压器绝缘状态评估方法[J].电工技术学报,2012,27(5):13-20. Zhang Yiyi,Liao Ruijin,Yang Lijun,et al.An assessment method for insulation condition of power transformer based upon cloud model[J].Transactions of China Electrotechnical Society,2012,27(5):13-20. [13]云玉新,张晓星,赵笑笑,等.SF6分解物SO2、H2S、HF、CO的红外吸收特性分析[J].高电压技术,2013,39(11):2650-2655. Yun Yuxin,Zhang Xiaoxing,Zhao Xiaoxiao,et al.Infrared absorption properties of SF6 gas-decomposition products SO2,H2S,HF and CO[J].High Voltage Engineering,2013,39(11):2650-2655. [14]裘吟君,唐炬,范敏,等.SF6局部放电分解产生SOF2特征组分的光声光谱检测[J].高电压技术,2013,39(5):1163-1169. Qiu Yinjun,Tang Ju,Fan Min,et al.Photoacoustic spectroscopy detection of SOF2 characteristic component engendered in SF6 decomposition under partial discharge[J].High Voltage Engineering,2013,39(5):1163-1169. [15]唐炬,朱黎明,刘帆,等.应用光声技术的SF6分解组分检测装置研制[J].高电压技术,2011,37(6):1313-1320. Tang Ju,Zhu Liming,Liu Fan,et al.Development of SF6 decomposition components detection device using acoustic technology[J].High Voltage Engineering,2011,37(6):1313-1320. [16]陈伟根,刘冰洁,胡金星,等.微弱气体光声光谱监测光声信号影响因素分析[J].重庆大学学报,2011,34(2):7-13. Chen Weigen,Liu Bingjie,Hu Jinxing,et al.Influential factors analysis on photoacoustic signal of photoacoustic spectroscopy monitoring trace gases[J].Journal of Chongqing University(Natural Science Edition),2011,34(2):7-13. [17]王新锋,吴次南,周章渝,等.光声光谱技术中斩光频率对光声信号影响的研究[J].贵州大学学报,2007,24(4):360-361. Wang Xinfeng,Wu Cinan,Zhou Zhangyu,et al.In the photoacoustic spectrum technology modulation frequency to the photoacoustic signal influence research[J].Journal of Guizhou University,2007,24(4):360-361. [18]蒙瑰,刘先勇,袁长迎,等.光声光谱气体检测系统中气体湿度的影响研究[J].光谱学与光谱分析,2011,31(7):1819-1822. Meng Gui,Liu Xianyong,Yuan Changying,et al.Researches on the effect of gas humidity on photoacoustic spectroscopy gas detection system[J].Spectroscopy and Spectral Analysis,2011,31(7):1819-1822. [19]陈伟根,刘冰洁,周恒逸,等.变压器油中溶解气体光声光谱检测的温度特性[J].电工技术学报,2010,25(11):15-20. Chen Weigen,Liu Bingjie,Zhou Hengyi,et al.The temperature characteristics of photoacoustic spectroscopy detection for dissolved gases in transformer oil[J].Transactions of China Electrotechnical Society,2010,25(11):15-20. [20]Rothman L S,Gordon I E,Barbe A,et a1.The HITRAN 2012 molecular spectroscopic database[J].Journal of Quantitative Spectroscopy and Radiative Transfer,2013,130:4-50. [21]Demtrder W.Laser Spectroscopy Vol.1:Basic Principles[M].Springer,Berlin:2008. [22]IEC.IEC 60567 Oil-filled electrical equipment-Sampling of gases and analysis of free and dissolved gases-Guidance[S]. [23]Kittle C.Elementary statistical physics[M].Wiley,New York:1958. [24]Rothman L S,Gordon I E,Barbe A,et al.The HITRAN 2008 molecular spectroscopic database[J].Journal of Quantitative Spectroscopy & Radiative Transfer,2009,110(9/10,SI):533-572.