Application of Polymers Membrane in Dissolved Gas Analysis: a Review
Chen Tunan1,2, Ma Fengxiang3, Wang Liufang3, Han Dong1,2, Zhang Guoqiang1,2
1. Institute of Electrical Engineering Chinese Academy of Sciences Beijing 100190 China; 2. University of Chinese Academy of Sciences Beijing 100049 China; 3. Electrical Power Research Institute Anhui Electrical Power Company Ltd State Grid Hefei 230601 China
Abstract:Dissolved gas analysis (DGA) is the most approved method for transformer insulation state detection. Meanwhile, oil-gas separation technique plays a significant part in DGA. For oil-gas separation, membrane technique is considered as a novel and promising method. Compared with conventional methods, membrane technique possesses several merits, such as simple structure, small size and maintain-free. Therefore, it has become the focus in DGA field. A review of recent researches about polymers membranes applied in DGA was provided in this paper, which included research status of both the material and the structure of polymers membranes. Then, the characteristics of several typical polymers membranes were summarized for comparison. Lasty, based on current research results, the development trends of polymers membranes for DGA were proposed.
陈图南, 马凤翔, 王刘芳, 韩冬, 张国强. 高分子渗透膜在变压器油中溶解气体分析中的应用[J]. 电工技术学报, 2022, 37(3): 750-766.
Chen Tunan, Ma Fengxiang, Wang Liufang, Han Dong, Zhang Guoqiang. Application of Polymers Membrane in Dissolved Gas Analysis: a Review. Transactions of China Electrotechnical Society, 2022, 37(3): 750-766.
[1] 杨峰, 唐超, 周渠, 等. 基于等效电路的油纸绝缘系统受潮状态分析[J]. 电工技术学报, 2020, 35(21): 4586-4596. Yang Feng, Tang Chao, Zhou Qu, et al.Analyzing the moisture state of oil-paper insulation system using an equivalent circuital model[J]. Transactions of China Electrotechnical Society, 2020, 35(21): 4586-4596. [2] 张永泽, 唐炬, 潘成, 等. 温度对流动变压器油中悬移气泡局部放电特性的影响与作用机制[J]. 电工技术学报, 2020, 35(6): 1357-1367. Zhang Yongze, Tang Ju, Pan Cheng, et al.Effects of temperature on partial discharge characteristics induced by suspended bubbles in flowing transformer oil and the mechanism[J]. Transactions of China Electrotechnical Society, 2020, 35(6): 1357-1367. [3] 张燕, 方瑞明. 基于油中溶解气体动态网络标志物模型的变压器缺陷预警与辨识[J]. 电工技术学报, 2020, 35(9): 2032-2041. Zhang Yan, Fang Ruiming.Fault detection and identification of transformer based on dynamical network marker model of dissolved gas in oil[J]. Transactions of China Electrotechnical Society, 2020, 35(9): 2032-2041. [4] 李恩文, 王力农, 宋斌, 等. 基于混沌序列的变压器油色谱数据并行聚类分析[J]. 电工技术学报, 2019, 34(24): 5104-5114. Li Enwen, Wang Linong, Song Bin, et al.Parallel clustering analysis of dissolved gas analysis data based on chaotic sequences[J]. Transactions of China Electrotechnical Society, 2019, 34(24): 5104-5114. [5] 齐波, 张鹏, 荣智海, 等. 基于数据驱动和多判据融合的油色谱监测传感器有效性评估方法[J]. 电网技术, 2017, 41(11): 3662-3669. Qi Bo, Zhang Peng, Rong Zhiha, et al.Validity assessment method of DGA sensors based on data driven and multiple criterion integration[J]. Power System Technology, 2017, 41(11): 3662-3669. [6] 崔鸿飞. 变压器油溶解气分离及光声检测技术研究[D]. 大连: 大连理工大学, 2014. [7] 查申龙. 变压器故障气体宽带光声光谱技术研究[D]. 合肥: 中国科学技术大学, 2017. [8] 徐懿俊. 变压器油中溶解性气体DGA检测方法的研究[D]. 上海: 复旦大学, 2011. [9] Ma Liang-Chih, Chen Chuan, Lin Jerry Y S. Teflon AF2400 hollow fiber membrane contactor for dissolved gas-in-oil extraction: mass transfer characteristics[J]. Industrial & Engineering Chemistry Research, 2020, 59(38): 16795-16804. [10] Hamidreza Sanaeepur, Abtin Ebadi Amooghin, Samaneh Bandehali, et al.Polyimides in membrane gas separation: monomer’s molecular design and structural engineering[J]. Progress in Polymer Science, 2019, 91: 80-125. [11] Lavanya C, Geetha Balakrishna R.Naturally derived polysaccharides-modified PSF membranes: a potency in enriching the antifouling nature of membranes[J]. Separation and Purification Technology, 2020, 230: 115887. [12] Feng Shasha, Zhong Zhaoxiang, Wang Yong, et al.Progress and perspectives in PTFE membrane: Preparation, modification, and applications[J]. Journal of Membrane Science, 2018, 549: 332-349. [13] 王湛, 王志, 高学理. 膜分离技术基础[M]. 3 版. 北京: 化学工业出版社, 2018. [14] Lu Xueting, Pu Yanfeng, Li Lei, et al.Preparation of metal-organic frameworks Cu3(BTC)2 with amino-functionalization for CO2 adsorption[J]. Journal of Fuel Chemistry and Technology, 2019, 47(3): 338-343. [15] 王天龙, 张燕, 王新红, 等. 类沸石咪唑酯骨架材料(ZIFs)的研究进展[J]. 化工进展, 2015, 34(11): 3959-3978. Wang Tianlong, Zhang Yan, Wang Xinhong, et al.Research progress in zeoliticimidazolate frameworks (ZIFs)[J]. Chemical Industry and Engineering Progress, 2015, 34(11): 3959-3978. [16] 李洋流, 赵学增, 郭春志, 等. 基于膜分离的变压器在线监测系统中气体体积分数的预测算法[J]. 电力自动化设备, 2010, 30(12): 36-41. Li Yangliu, Zhao Xuezeng, Guo Chunzhi, et al.Gas concentration prediction algorithm based on membrane extraction for transformer online monitoring system[J]. Electric Power Automation Equipment, 2010, 30(12): 36-41. [17] Lei Wang, Jean-Pierre Corriou, Christophe Castel, et al.Transport of gases in glassy polymers under transient conditions: limit-behavior investigations of dual-mode sorption theory[J]. Industrial and Engineering Chemistry Research, 2013, 52(3): 1089-1101. [18] Tawfik Abdo Saleh, Gupta V K.Applications of nanomaterial-polymer membranes for oil and gas separation, nanomaterial and polymer membranes[M]. Amsterdam: Elsevier, 2016. [19] Marcel Mulder.膜技术基本原理[M]. 李琳译. 北京: 清华大学出版社, 1999. [20] Xue Ning, William J Koros.Carbon molecular sieve membranes derived from Matrimid® polyimide for nitrogen/methane separation[J]. Carbon, 2014, 66: 511-522. [21] William O Berndt.Membrane physiology (membrane transport mechanisms)[M/OL].4th Ed. Cytology and Cell Physiology, INC: Academic Press, 1987. [22] Jose Manuel Perez-Francisco, Jose Luis Santiago-García, María Isabel Loría-Bastarrachea, et al. CMS membranes from PBI/PI blends: temperature effect on gas transport and separation performance[J]. Journal of Membrane Science, 2020, 597: 117703. [23] Sergio Bustamante, Mario Manana, Alberto Arroyo, et al.Dissolved gas analysis equipment for online monitoring of transformer oil: a review[J]. Sensors, 2019, 19(19): 4-12. [24] 中国人民共和国国家质量监督检验检疫总局. GB/T 7252—2001变压器油中溶解气体分析和判断导则[S]. 2001. [25] Ma Fengxiang, Liao Zhenghai, Zhao Yue, et al.Detection of trace C2H2 in N2 buffer gas with cantilever-enhanced photoacoustic spectrometer[J]. Optik, 2021, 232: 166525. [26] Ma Yufei, Qiao Shunda, He Ying, et al.Highly sensitive acetylene detection based on multi-pass retro-reflection-cavity-enhanced photoacoustic spectroscopy and a fiber amplified diode laser[J]. Optics Express, 2019, 27(10): 14163-14172. [27] 中华人民共和国国家质量监督检验检疫总局, 中国国家标准化管理委员会. 电力变压器第2部分:液浸式变压器的温升[S]. [28] Chen Min, Ding Weijie, Zhou Ming, et al.Fouling mechanism of PVDF ultrafiltration membrane for secondary effluent treatment from paper mills[J]. Chemical Engineering Research and Design, 2021, 167: 37-45. [29] Hossein Karimi, Majid Bazrgar Bajestani, Seyyed Abbas Mousavi, et al.Polyamide membrane surface and bulk modification using humid environment as a new heat curing medium[J/OL]. Journal of Membrane Science, 2017, 523: 129-137. [30] Zhan Ziming, Tang Yongjian, Zhu Kake, et al.Coupling heat curing and surface modification for the fabrication of high permselectivity polyamide nanofiltration membranes[J]. Journal of Membrane Science, 2021, 623: 119073. [31] 魏柯, 张道海, 秦舒浩, 等. 聚砜分离膜的亲水改性研究进展[J]. 高分子材料科学与工程, 2018, 34(8): 179-183. Wei Ke, Zhang Daohai, Qin Shuhao.Advances in hydrophilic modification of polysulfone separation membrane[J]. Polymer Materials Science & Engineering, 2018, 34(8): 179-183. [32] In Hwan Shin, Seungkwan Hong, Seung Joo Lim, et al.Surface modification of PVDF membrane by radiation-induced graft polymerization for novel membrane bioreactor[J/OL]. Journal of Industrial and Engineering Chemistry, 2017, 46: 103-110. [33] Vatsal Shah, Wang Bo, Li Kang.Blending modification to porous polyvinylidene fluoride (PVDF) membranes prepared via combined crystallisation and diffusion (CCD) technique[J/OL]. Journal of Membrane Science, 2021, 618: 118708. [34] 江爱朋, 程文, 姜周曙, 等. 卷式反渗透海水淡化系统膜清洗与更换策略优化[J]. 化工学报, 2015, 66(10): 4092-4100. Jiang Aipeng, Cheng Wen, Jiang Zhoushu, et al.A strategy of membrane cleaning and replacing schedule for spiral-wound SWRO system[J]. CIESC Journal, 2015, 66(10): 4092-4100. [35] Alexander A Artyukhov, Mikhail I Shtilman, Andrey N Kuskov, et al.Macroporous polymeric hydrogels formed from acrylate modified polyvinyl alcohol macromers[J]. Journal of Polymer Research, 2011, 18(4): 667-673. [36] 马超, 黄海涛, 顾计友, 等. 高分子分离膜材料及其研究进展[J]. 材料导报A:综述篇, 2016, 30(5): 144-157. Ma Chao, Huang Haitao, Gu Jiyou, et al.Polymer separation membrane materials and their research progress[J]. Materials Report A: Review, 2016, 30(5): 144-157. [37] Lloyd M Robeson.Correlation of separation factor versus permeability for polymeric membranes[J]. Journal of Membrane Science, 1991, 62(2): 165-185. [38] Maria I Loría-Bastarrachea, Manuel Aguilar-Vega. Membranes from rigid block hexafluoro copolyaramides: effect of block lengths on gas permeation and ideal separation factors[J]. Journal of Membrane Science, 2013, 443(15): 36-44. [39] Laurence W McKeen. Fatigue and tribological properties of plastics and elastomers[M]. Amsterdan: Elsevier, 2010. [40] 刘冰肖. 半芳香族耐高温聚酰胺及其复合材料的制备与性能研究[D]. 太原: 中北大学, 2019. [41] Sedra Tul Muntha, Ayesha Kausar, Muhammad Siddiq.Progress in applications of polymer-based membranes in gas separation technology[J]. Polymer-Plastics Technology and Engineering, 2016, 55(12): 1282-1298. [42] Cristian-Dragos Varganici, Dan Rosu, Cristian Barbu-Mic, et al.On the thermal stability of some aromatic-aliphatic polyimides[J]. Journal of Analytical and Applied Pyrolysis, 2015, 113: 390-401. [43] Naiying Du, Ho Bum Park, Mauro M Dal-Cin, et al. Advances in high permeability polymeric membrane materials for CO2 separations[J]. Energy and Environmental Science, 2012, 5(6): 7306-7322. [44] Atsushi Morikawa.High Performance Polymers and Engineering Plastics[M/OL]. New York USA: John Wiley & Sons, Inc., 2011. [45] 李洋流. 基于膜分离与光声光谱的绝缘油中溶解气体在线分析技术[D]. 哈尔滨: 哈尔滨工业大学, 2011. [46] Tsukioka H, Sugawara K, Mori E.Apparatus for continuously monitoring hydrogen gas dissolved in transformer oil[J]. IEEE Transactions on Electrical Insulation, 1981, 16(6): 502-509. [47] Hunter J C, Black G.Methods and systems for selective hydrogen gas extraction for dissolved gas analysis applications: US2017/0165592 A1[P]. 2017. [48] Anindita Ghosh, Suman Kumar Sen, Susanta Banerjee, et al.Solubility improvements in aromatic polyimides by macromolecular engineering[J]. RSC Advances, 2012, 2(14): 5900-5926. [49] Melinda L Jue, Ryan P Lively.Targeted gas separations through polymer membrane functionalization[J]. Reactive and Functional Polymers, 2015, 86: 88-110. [50] Xiao Youchang, Bee Ting Low, Seyed Saeid Hosseini, et al.The strategies of molecular architecture and modification of polyimide-based membranes for CO2 removal from natural gas-a review[J]. Progress in Polymer Science, 2009, 34(6): 561-580. [51] Yun-Hi Kim, Hyung-Sun Kim, Soon-Ki Kwon.Synthesis and characterization of highly soluble and oxygen permeable new polyimides based on twisted biphenyl dianhydride and spirobifluorene diamine[J]. Macromolecules, 2005, 38(19): 7950-7956. [52] Michael D Guiver, Gilles P Robertson, Ying Dai, et al.Structural characterization and gas-transport properties of brominated Matrimid polyimide[J]. Journal of Polymer Science, Part A: Polymer Chemistry, 2002, 40(23): 4193-4204. [53] Katrien Vanherck, Guy Koeckelberghs, Ivo F J Vankelecom. Crosslinking polyimides for membrane applications: a review[J]. Progress in Polymer Science, 2013, 38(6): 874-896. [54] 芦霞. 改性聚酰亚胺膜制备及CO2分离性能研究[D]. 天津: 天津大学, 2014. [55] 张斌, 刘帅, 王丽华, 等. 磺化聚酰亚胺酸碱复合膜的制备及其在全钒液流电池中的应用[J]. 高分子学报, 2015, 4: 418-426. Zhang Bin, Liu Shuai, Wang Lihua, et al.Sulfonated polyimide acid-base blend membranes for vanadium redox flow cell application[J]. Acta Polymerica Sinica, 2015, 4: 418-426. [56] 李玉邯, 金日哲, 高连勋. 侧链含氮原子磺化聚酰亚胺膜材料的制备及其性能研究[J]. 高分子学报, 2014, 8: 1096-1102. Li Yuhan, Jin Rizhe, Gao Lianxun.Preparation and characterization of sulfonated polyimide membranes containing nitrogen atoms in the side chain[J]. Acta Polymerica Sinica, 2014, 8: 1096-1102. [57] Xiao D M, Liu H L, Dong X, et al.Permeability study of high polymer membranes for gas-oil separation[C]// 2000 IEEE Power Engineering Society, Conference Proceedings, Singapore, 2000, 3: 2229-2232. [58] 董瑞. PVDF/PTFE复合膜的制备及其性能研究旋涂[D]. 广州: 华南理工大学, 2013. [59] 李国强. 变压器油绝缘在线监测技术研究[D]. 哈尔滨: 哈尔滨工业大学, 2008. [60] 丁家峰. 基于SOFC的变压器油中溶解气体检测机理与技术研究[D]. 长沙: 中南大学, 2012. [61] 梅德俊. PTFE平板膜的亲水改性研究[D]. 杭州: 浙江理工大学, 2015. [62] Song Haiming, Yu Hongwei, Zhu Lijing, et al.Durable hydrophilic surface modification for PTFE hollow fiber membranes[J]. Reactive and Functional Polymers, 2017, 114: 110-117. [63] Wang Jieqi, Li Chengcai, Wang Feng, et al.Hydrophilic modification of PTFE microfiltration flat membrane by crosslinking OCMCS-PEI to enhance anti-fouling property[J]. Progress in Organic Coatings, 2019, 135: 565-573. [64] Yu Sha, Kang Guodong, Zhu Zhihao, et al.Nafion-PTFE hollow fiber composite membranes for improvement of anti-fouling and anti-wetting properties in vacuum membrane distillation[J/OL]. Journal of Membrane Science, 2021, 620: 118915. [65] 栗小茜, 葛正浩. 无机材料填充改性PTFE复合材料研究进展[J]. 中国塑料, 2020, 34(1): 92-101. Li Xiaoqian,Ge Zhenghao.A review on PTFE composites filled with inorganic materials[J]. China Plastic, 2020, 34(1): 92-101. [66] 陈川, 丁一, 刘昕, 等. α-Al2O3/γ-Al2O3/Teflon AF2400中空纤维油气分离膜的制备及性能研究[J]. 功能材料, 2019, 12(50): 12178-12182, 12189. Chen Chuan, Ding Yi, Liu Xin, et al.Preparation and properties of α-Al2O3/γ-Al2O3/Teflon AF2400 hollow fiber oil-gas separation membrane[J]. Journal of Functional Materials, 2019, 50(12): 12178-12182, 12189. [67] Ma Liang-Chih, Chen Chuan, Chen Chien-Hua, et al.Gas transport properties of teflon AF2400/ceramic composite hollow fiber membranes in dissolved-gas-in-oil extraction[J]. Industrial and Engineering Chemistry Research, 2020, 59(12): 5392-5401. [68] Hong Zhang, Abul Hussam, Stephen G Weber.Properties and transport behavior of perfluorotripentylamine (FC-70)-doped amorphous teflon AF2400 films[J]. Journal of the American Chemical Society, 2010, 132(50): 17867-17879. [69] Johannes Carolus Jansena, Karel Friessb, Enrico Drioli.Organic vapour transport in glassy perfluoropolymer membranes: a simple semi-quantitative approach to analyze clustering phenomena by time lag measurements[J]. Journal of Membrane Science, 2011, 367(1-2): 141-151. [70] Han Yuwang, Ding Fei, Hao Chanxi, et al.The oil-gas separation characteristics of ceramic/Teflon AF2400 composite membrane[J]. Separation and Purification Technology, 2012, 88: 19-23. [71] 褚佳欢, 占南, 韩毓旺. 基于Teflon AF/陶瓷复合膜和电化学传感器的变压器油中溶解气体的在线监测系统[J]. 理化检验(化学分册), 2019, 55: 530-535. Zhu Jiahuan, Zhan Nan, Han Yuwang.On-line monitoring system for dissolved gases in transformer oil using Teflon AF/Ceramic composite membrane and electrochemical sensors[J]. PTCA (Part B: Chem. Anal.) , 2019, 55: 530-535. [72] Liu Sainan, Ma Liang-Chih, Chen Chien-Hua, et al.Highly gas permeable, ultrathin Teflon AF2400/γ-alumina composite hollow fiber membranes for dissolved gas analysis[J]. Journal of Membrane Science, 2017, 540(4): 243-250. [73] 陈伟根. 以油中多种气体为特征量的变压器绝缘在线监测及故障诊断技术研究[D]. 重庆: 重庆大学, 2003. [74] 安晨光. 变压器油中溶解气体在线监测关键技术研究[D]. 长沙: 中南大学, 2008. [75] 马凤翔, 田宇, 陈珂, 等. 基于微型光声传感器的油中溶解气体检测技术[J]. 光学学报, 2020, 40(7): 0730003. Ma Fengxiang, Tian Yu, Chen Ke, et al.Technique for detection of dissolved gas in oil based on miniature photoacoustic sensor[J]. Acta Optica Sinica, 2020, 40(7): 0730003. [76] 李鑫, 李海楠, 王国华, 等. 硫酸钡改性FEP导管的挤出成型[J]. 塑料, 2013, 42(6): 58-61. Li Xin,Li Hainan,Wang Guohua, et al.Extrusion process of FEP catheters modified by barium sulfate[J]. Plastic, 2013, 42(6): 58-61. [77] Wu Yanjie, Huang Qinglin, Xiao Changfa, et al.Study on the effects and properties of PVDF/FEP blend porous membrane[J]. Desalination, 2014, 353: 118-124. [78] 王悦, 高超锋, 黄捷, 等. 石墨烯及聚苯酯改性共填充FEP性能研究[J]. 现代塑料加工应用, 2020, 32(5): 18-20. Wang Yue, Gao Chaofeng, Huang Jie, et al.Study on properties of graphene and polypohenyl ester co-filled FEP[J]. Modern Plastics Processing and Applications, 2020, 32(5): 18-20. [79] 苗中青. 亲水性聚全氟乙丙烯中空纤维膜的制备研究[D]. 天津: 天津工业大学, 2013. [80] 闫二锦. 添加剂对聚砜超滤膜的微细结构及亲水性能的影响[D]. 杭州: 浙江理工大学, 2016. [81] 单华俊. 聚醚砜涂料的制备及防腐性能研究[D]. 吉林: 吉林大学, 2014. [82] 赵翌帆. 聚砜类超滤膜表面两性离子化及其性能的研究[D]. 杭州: 浙江大学, 2015. [83] 周道伟, 姚金志, 吴刚, 等. 聚二甲基硅氧烷中空膜在钻井液轻烃气体分离中的应用[J]. 厦门大学学报(自然科学版), 2015, 54(4): 450-454. Zhou Daowei, Yao Jinzhi, Wu Gang, et al.Application of PDMS hollow-fiber membrane in separation of ligh hydrocarbon gas from drilling mud[J]. Journal of Xiamen University (Nature Science), 2015, 54(4): 450-454. [84] 王鸿, 李琳, 王春雷, 等. 内嵌柔性支撑体PDMS复合膜的制备及其C3气体/N2分离性能研究[J]. 高校化学工程学报, 2016, 30(5): 1036-1042. Wang Hong, Li Lin, Wang Chunlei, et al.Preparation of PDMS composite membranes with flexible supports and their performance in C3 hydrocarbon gases/N2 separation[J]. Journal of Chemical Engineering of Chinese Universities, 2016, 30(5): 1036-1042. [85] Liu Fu, Hashim N Awanis, Liu Yutie, et al.Progress in the production and modification of PVDF membranes[J]. Journal of Membrane Science, 2011, 375(1-2): 1-27. [86] 蒋俊. 变压器油中溶解气体在线监测系统研究[D]. 武汉: 湖北工业大学, 2018. [87] Zhou Xiaoying, Loo Hongen, Bai Renbi.A novel membrane showing both hydrophilic and oleophobic surface properties and its non-fouling performances for potential water treatment applications[J]. Journal of Membrane Science, 2013, 436: 47-56. [88] Chen Lifang, Hou Zhengchi, Lu Xiaofeng, et al.Antifouling microfiltration membranes prepared from poly(vinylidene fluoride)-graft-poly(N-vinyl pyrrolidone) powders synthesized via pre-irradiation induced graft polymerization[J]. Journal of Applied Polymer Science, 2013, 128(6): 3949-3956. [89] 孙才新, 陈伟根, 李俭. 电气设备油中气体在线监测与故障诊断技术[M]. 北京: 科学出版社, 2003. [90] 王毓红. 电力变压器色谱在线监测系统的研究[D]. 上海: 上海交通大学, 2008. [91] Tsukioka H, Sugawara K, Mori E, et al.New apparatus for detecting H2, CO, and CH4 dissolved in transformer oil[J]. IEEE Transactions on Electrical Insulation, 1983, 18(4): 409-419. [92] 王涛, 展侠, 李继定. 平板膜组件内部流体流动状态的可视化[J]. 化工学报, 2014, 65(1): 71-77. Wang Tao, Zhan Xia, Li Jiding.Flow visualization through channels in plate-and-frame modules[J]. CIESC Journal, 2014, 65(1): 71-77. [93] 赵立华, 李洋流, 李国强. 基于气体传感器的变压器在线DGA系统的研究[J]. 传感器与微系统, 2009, 28(11): 46-48. Zhao Lihua, Li Yangliu, Li Guoqiang.Study of on-line transformer DGA system based on gas sensor[J]. Transducer and Microsystem Technologies, 2009, 28(11): 46-48. [94] 赵明清. 油中气相色谱在线分析装置应用于三绕组变压器的研究[D]. 重庆: 重庆大学, 2002. [95] General Electric Company. Hydran 201Ti [EB/OL]. (Accessed2021-01-26). https://www.gegridsolutions. com/md/catalog/hydran201ti.htm. [96] 阮雪华. 气体膜分离及其梯级耦合流程的设计与优化[D]. 大连: 大连理工大学, 2014. [97] Schwinge J, Neal P R, Wiley D E, et al.Spiral wound modules and spacers: review and analysis[J]. Journal of Membrane Science, 2004, 242(1-2): 129-153. [98] 刘彦涛. 超滤/反渗透双膜法在海水淡化中的应用研究[D]. 北京: 清华大学, 2015. [99] 张海芬, 黄庆林, 肖长发, 等. 无机粒子杂化FEP微孔膜结构与性能研究[J]. 高分子学报, 2015, 9: 1078-1084. Zhang Haifen, Huang Qinglin, Xiao Changfa, et al.Structure and performance studies of the FEP/ inorganic particles hybrid microporous membranes[J]. Acta Polymerica Sinica, 2015, 9: 1078-1084. [100] 周婧也. 平板油气分离膜制备及回收油船排放VOCs[D]. 舟山: 浙江海洋大学, 2019. [101] Cheng Jinxue, Huang Qinglin, Huang Yan, et al.Study on a novel PTFE membrane with regular geometric pore structures fabricated by near-field electrospinning, and its applications[J/OL]. Journal of Membrane Science, 2020, 603: 118014. [102] 郝劢, 龙震泽, 陈伟根. 一种新型中空纤维膜的油气渗透特性[J]. 高压电器, 2012, 48(5): 105-110. Hao Mai, Long Zhenze, Chen Weigen.Oil-gas permeability of a new hollow fiber membrane[J]. High Voltage Apparatus, 2012, 48(5): 105-110. [103] ABB. CoreSense M10 Multi-Gas DGA Analyzer [EB/OL](Accessed2020-11-23). https://new.abb.com/ products/transformers/service/advanced-services/coresense. [104] 昆山和智电气设备有限公司. HPAS-1000变压器光声光谱在线监测系统[EB/OL]. (Accessed 2020-12-04). http://www.hz-elec.net/pd.asp?A=14. [105] 范寒寒. 石墨改性聚全氟乙丙烯导热中空纤维及其换热器的研制[D]. 天津: 天津大学, 2012. [106] 张华鹏, 朱海霖, 王峰, 等. 聚四氟乙烯中空纤维膜的制备[J]. 膜科学与技术, 2013, 33(1): 17-21. Zhang Huapeng, Zhu Hailin, Wang Feng, et al.Studies on the preparation of PTFE hollow fiber membrane[J]. Membrane Science and Technology, 2013, 33(1): 17-21. [107] Li Kuiling, Zhang Yong, Xu Lili, et al.Optimizing stretching conditions in fabrication of PTFE hollow fiber membrane for performance improvement in membrane distillation[J]. Journal of Membrane Science, 2018, 550: 126-135. [108] 陈伟根, 时晶, 徐海霞, 等. 掺杂Al2O3纳米中空纤维膜的油气渗透特性研究[J]. 电工技术学报, 2015, 30(6): 240-246. Chen Weigen, Shi Jing, Xu Haixia, et al.Dissolved gas permeation characteristics research based on hollow fiber membrane doped with nano-oxide Al2O3[J]. Transactions of China Electrotechnical Society, 2015, 30(6): 240-246. [109] Su Chunlei, Li Yuping, Cao Hongbin, et al.Novel PTFE hollow fiber membrane fabricated by emulsion electrospinning and sintering for membrane distillation[J]. Journal of Membrane Science, 2019, 583: 200-208. [110] 国家电网有限公司. Q/GDW 10536-2020变压器油中溶解气体在线监测装置技术规范[S]. 2020. [111] 河南中分仪器股份有限公司. ZF-301Q全自动变压器油分析气相色谱仪[EB/OL] (Accessed 2020-04-20). http://www.zhongfenyiqi.com/pd.jsp?id=50#_pp= 103_455. [112] 思源电气. 油光谱[EB/OL].(Accessed 2020-11-23). http://www.sieyuan.com/index.aspx?cat_code=ygp&article_id=3455.