MCM-41表面改性及MCM-41/环氧树脂复合材料陷阱特性

doi:10.19595/j.cnki.1000-6753.tces.151998

Abstract
Figure/Table
References
Related Citation (5)

Download: PDF (25018 KB) HTML (1 KB)
Export: BibTeX | EndNote (RIS)

Abstract In this paper, the MCM-41 was surface modified by the silane coupling agent KH550 before the preparation of MCM-41/EP nano-composite. Moreover, the thermogravimetric analysis, Fourier transform infrared spectroscopy, small angle X-ray diffraction and N₂ adsorption-desorption isotherms were used to characterize the surface structure of MCM-41 before and after surface modification. The in-situ polymerization was employed to prepare the MCM-41/EP Nano-composite with different percentages of MCM-41. Then, the glass transition temperature of MCM-41/EP composite was measured by using the dynamic mechanical analyzer. The results showed that the glass transition temperature of MCM-41/EP composite increased with the increase of MCM-41 percentage. Finally, the trap parameter of the composite was measured by the thermally stimulated depolarization current. It was shown that, with the increase of MCM-41, the trap depth became shallow, and the quantity of trapped charge decreased significantly.

Key words： MCM-41 surface modification MCM-41/EP glass transition temperature trap characteristic

Received: 09 December 2016 Published: 24 May 2018

PACS:

TM215.1

	Service

	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	Luo Pan
	Xu Man
	Wang Shaohui
	Li Peng
	Zhang Yihan
	Xu Yang
	Xie Darong

Cite this article:

Luo Pan,Xu Man,Wang Shaohui等. MCM-41 Surface Modification and Trap Characteristic of MCM-41/EP Composites[J]. Transactions of China Electrotechnical Society, 2018, 33(10): 2245-2252.

URL:

https://dgjsxb.ces-transaction.com/EN/10.19595/j.cnki.1000-6753.tces.151998 OR https://dgjsxb.ces-transaction.com/EN/Y2018/V33/I10/2245

[1] 张代东, 吴润. 材料科学基础[M]. 北京: 北京大学出版社, 2011.
[2] 巫松桢, 谢大荣. 电气绝缘材料科学与工程[M]. 西安: 西安交通大学出版社, 1996.
[3] 张明艳, 王晨, 吴淑龙, 等. 碳纳米管、蒙脱土共掺杂环氧树脂复合材料介电性能研究[J]. 电工技术学报, 2016, 31(10): 151-158.
Zhang Mingyan, Wang Chen, Wu Shulong, et al.Research on dielectric properties of epoxy resin composites doped with carbon nanotubes and montmorillonite[J]. Transactions of China Elec- trotechnical Society, 2016, 31(10): 151-158.
[4] 王旗, 李喆, 尹毅, 等. 微/纳米氧化铝/环氧树脂复合材料抑制电树枝生长能力的研究[J]. 电工技术学报, 2015, 30(6): 255-260.
Wang Qi, Li Zhe, Yin Yi, et al.The effect of micro and nano alumina on the ability of impedance on the electrical tree of epoxy resin[J]. Transactions of China Electrotechnical Society, 2015, 30(6): 255-260.
[5] Li S T, Yin G L, Bai S N, et al.A new potential barrier model in epoxy resin nanodielectrics[J]. IEEE Transactions on Dielectrics and Electrical Insulation, 2011, 18(5): 1535-1543.
[6] Lewis T J.Interfaces are the dominant feature of dielectrics at the nanometric level[J]. IEEE Transa- ctions on Dielectrics and Electrical Insulation, 2004, 11(5): 739-753.
[7] Tanaka T, Kozako M, Fuse N, et al.Proposal of a multi-core model for polymer nanocomposite dielectrics[J]. IEEE Transactions on Dielectrics and Electrical Insulation, 2005, 12(4): 669-681.
[8] Tanaka T, Montanari G C, Mulhaupt R.Polymer nanocomposites as dielectrics and electrical insulation- perspectives for processing technologies, material characterization and future applications[J]. IEEE Transactions on Dielectrics and Electrical Insulation, 2004, 11(5): 763-784.
[9] Lau K, Vaughan A, Chen G.Nanodielectrics: opportunities and challenges[J]. IEEE Electrical Insulation Magazine, 2015, 31(4): 45-54.
[10] Tanaka T, Imai T.Advances in nanodielectric materials over the past 50 years[J]. IEEE Electrical Insulation Magazine, 2013, 29(1): 10-23.
[11] Cherney E A.Nanodielectrics applications-today and tomorrow[J]. IEEE Electrical Insulation Magazine, 2013, 29(6):59-65.
[12] 赵东元, 万颍, 周午纵. 有序介孔分子筛材料[M]. 北京: 高等教育出版社, 2013.
[13] 焦剑, 张佳赟. 环氧树脂/介孔SiO₂复合材料的结构与性能[J]. 中国塑料, 2008, 22(9): 57-62.
Jiao Jian, Zhang Jiayun.Textural properties of epoxy resin/mesostructured silica mesocomposites[J]. China Plastics, 2008, 22(9): 57-62.
[14] 王娜, 张静, 戴彩云, 等. 环氧树脂/纳米介孔分子筛复合材料的制备及性能研究[J]. 工程塑料应用, 2006, 34(5): 15-18.
Wang Na, Zhang Jing, Dai Caiyun, et al.Preparation and property of epoxy resin nano-sized mesoporous molecular sieve nanocomposite[J]. Composite Science and Technology, 2006, 34(5): 15-18.
[15] 张莉莉, 黄思共, 李湘祁. 介孔MCM-48粉体对环氧树脂性能影响[J]. 热固性树脂, 2009, 24(6): 41-43.
Zhang Lili, Huang Sigong, Li Xiangqi.Effect of mesoporous MCM-48 on mechanical and dielectric properties of epoxy resin[J]. Thermosetting Resin, 2009, 24(6): 41-43.
[16] 曹均助, 苏跃增, 周持兴. 介孔材料SBA-15/环氧树脂复合材料的制备和固化动力学[J]. 高分子材料科学与工程, 2011, 27(11): 133-136.
Cao Junzhu, Su Yuezeng, Zhou Chixing.Synthesis of mesoporous material SBA-15/Epoxy composite and cure Kinetics[J]. Polymer Materials Science and Engineering, 2011, 27(11): 133-136.
[17] Lin J, Wang X.Preparation, microstructure, and properties of novel low-κ brominated epoxy/meso- porous silica composites[J]. European Polymer Journal, 2008, 44(5): 1414-1427.
[18] Han B, Wang X, Sun Z, et al.Space charge suppression induced by deep traps in polyethylene/ zeolite nanocomposite[J]. Applied Physics Letters, 2013, 102(1): 012902-012904.
[19] Friedman H L.Kinetics of thermal degradation of charforming plastics from thermogravimetry app- lication to a phenolic plastic[J]. Journal of Polymer Science Part C: Polymer Symposia, 1964, 6(1): 183-195.
[20] 马晶. SBA-15(16)介孔分子筛的功能化修饰及其在多项催化中的应用[D]. 哈尔滨: 哈尔滨工业大学, 2011.
[21] 曹均助. 环氧树脂和介孔SBA-15复合材料制备和固化动力学的研究[D]. 上海: 上海交通大学, 2011.
[22] Baerlocher C, Mccusker L B.Practical aspects power diffraction data-analysis[J]. Studies in Surface Science & Catalysis, 1994, 85: 391-428.
[23] Yuanxin Zhou, Farhana Pervi, Lance Lewis.Experimental study on the thermal and mechanical properties of multi-walled carbon nanotube-reinforced epoxy[J]. Materials Science and Engineering: A, 2007, 452: 657-664.
[24] Tao Xie, Ingrid A.Rousseau, Facile tailoring of thermal transition temperatures of epoxy shape memory polymers[J]. Polymer, 2009, 50(8): 1852-1856.
[25] Starr F W, Schrøder T B, Glotzer S C. Effects of a nanoscopic filler on the structure and dynamics of a simulated polymer melt and the relationship to ultra-thin films[J]. Physical Review E, 2001, 64(2): 021802(1-5).
[26] 王力衡. 介质的热刺激电流理论及其应用[M]. 北京: 科学出版社, 1988.
[27] 田付强, 卜文斌, 杨春, 等. TSC测量技术中存在的若干问题的探讨[J]. 电工技术学报, 2010, 25(11): 21-28.
Tian Fuqiang, Bu Wenbin, Yang Chun, et al.Investigation of existing problems in thermally stimulated current measurement technique[J]. Transa- ctions of China Electrotechnical Society, 2010, 25(11): 21-28.
[28] 王暄, 赵晓旭, 雷清泉, 等. 复合热激电流曲线陷阱参数的计算[J]. 电工技术学报, 2000, 15(4): 84-87.
Wang Xuan, Zhao Xiaoxu, Lei Qingquan, et al.Calculation of the trapping parameters of composite thermally stimulated current curve[J]. Transactions of China Electrotechnical Society, 2000, 15(4): 84-87.