电工技术学报  2023, Vol. 38 Issue (8): 2265-2276    DOI: 10.19595/j.cnki.1000-6753.tces.220121
高电压与放电 |
ZnO@PS粒子分散特性及改性乙丙橡胶绝缘性能研究
刘凯, 张鹏鹏, 高波, 杨雁, 吴广宁
西南交通大学电气工程学院 成都 611756
Research on the Dispersion Characteristics of ZnO@PS Particles and the Insulation Characteristics of Modified Ethylene Propylene Rubber
Liu Kai, Zhang Pengpeng, Gao Bo, Yang Yan, Wu Guangning
School of Electrical Engineering Southwest Jiaotong University Chengdu 611756 China
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摘要 为研究核壳ZnO@PS粒子分散特性及其掺杂对三元乙丙橡胶(EPDM)绝缘性能的影响,该文采用聚合改性法制备了ZnO@PS复合颗粒,并利用透射电镜、粒度分析、红外光谱及热失重分析等测试手段对样品的形貌、结构和分散性进行了表征。另外,以ZnO@PS/EPDM复合材料为研究对象,研究了其电导特性、介电特性和耐电晕性能随纳米颗粒掺杂比例的变化规律。试验结果表明:改性纳米氧化锌(ZnO)、表面聚乙烯醇(PVA)及聚苯乙烯(PS)长链以无规则形式粘结,PVA作为“桥梁”交联多条PS长链,其对纳米ZnO表面羟基的去除效果明显,当PVA占比为6.32 %时包覆效果相对良好,团聚现象得到明显改善。同时由于ZnO@PS掺杂物的引入,使得ZnO@PS/EPDM复合材料具备了非线性均压特性,耐电晕放电能力也明显提升,且随着纳米颗粒掺杂比例的增加,其非线性特征更加明显,当ZnO@PS颗粒质量分数为5 %时,相比于未改性乙丙橡胶起晕电压增加了95.5 %,ZnO@PS复合颗粒在改性EPDM绝缘性能方面发挥了主要作用。研究结果对电缆终端功能性材料的制备具有重要的参考价值。
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刘凯
张鹏鹏
高波
杨雁
吴广宁
关键词 纳米ZnO悬浮聚合纳米掺杂电导特性介电特性电晕放电非线性    
Abstract:The cable terminal is an important component of electric locomotive high voltage cable, but it is also the weak link of the high voltage cable insulation system. In the operation of cable terminals, the “three junction points” (the outer semiconductor layer, the stress control pipe, and the main insulation layer) produce a concentrated electric field, leading to a partial discharge phenomenon, which seriously affects the safety and reliability of EMU operation. In order to solve effectively the problems of uneven electric field distribution and excessively high local field intensity at the end of vehicle cable, this paper studied the dispersion characteristics of core-shell ZnO@PS particles and the influence of doping on the insulation performance of EPDM rubber, explored the influence of ZnO@PS particles on the microscopic and dielectric properties of composite dielectric materials, and built the corona discharge model of needle-plate electrode. The effect of nano-particles with different doping ratios on the corona resistance of modified ethylene propylene rubber was analyzed.
Firstly, ZnO@PS composite particles were prepared by polymerization modification method. Then, the morphology, structure, and dispersion of the samples were characterized by transmission electron microscopy, particle size analysis, infrared spectroscopy, and thermogravimetric analysis. Secondly, with ZnO@PS /EPDM composite as the research object, the conductivity, dielectric properties and corona resistance with the doping ratio of nanoparticles werestudied. Moreover, the needle-plate electrode model was built to explore the corona discharge of composite dielectric material under anuneven electric field. The research results provide a reference for preparing cable terminal functional materials.
The microscopic characteristics of ZnO@PS composite particles were analyzed. TEM results show that the long chains of PVA/PS adhere to the ZnO surface in an irregular form, and the film-forming performance of PVA is remarkable. The particle size analysis shows that when PVA/ZnO=6.32(wt/wt) %, the average particle size is 132.42 nm, the PDI coefficient is 0.17, and the dispersion performance of composite particles is better. FTIR results show that PVA/PS modification has anoticeable effect on the removal of hydroxyl on the surface of nano-ZnO, and hydrogen bonds are formed at the interface of inorganic/organic molecules. TGA and DSC results show that the mass percentage of the nano-composite particles increases and the maximum mass loss fraction is 47.208 %.
The conductivity, dielectric properties, and corona discharge resistance characteristics of ZnO@PS/EPDM composites were studied. After doping nano-composite particles, the ZnO@PS/EPDM materials show nonlinear characteristics with the electric field change. With the increase of doping concentration, the nonlinear characteristics become more apparent, the nonlinear coefficient increases, and the initial field strength in the nonlinear region decreases.Compared with the unmodified EPDM, it is found that the corona resistance of the nanoparticle-modified EPDM composite is improved under the uneven electric field. When the doping amount of ZnO@PS particles is 5 %, the corona voltage increases by 95.5 % compared with the unmodified EPDM, and the UV photon count rate shows an apparent downward trend.
This paper can lay a theoretical foundation for applying nonlinear voltage equalization materials in cable terminals and provide a reference for preparing cable terminal functional materials.
Key wordsNano zinc oxide    suspension polymerization    nano-doping    conductivity characteristics    dielectric properties    corona discharge    non-linear   
收稿日期: 2022-01-20     
PACS: TM853  
基金资助:国家自然科学基金(52007158, 51907167)和牵引动力国家重点实验室开发课题(J0220602042102-41)资助项目
通讯作者: 高 波 男,1976年生,副教授,硕士生导师,研究方向为电气设备状态监测、故障诊断、故障预测。E-mail: bogao@home.swjtu.edu.cn   
作者简介: 刘 凯 男,1990年生,讲师,硕士生导师,研究方向为电气设备绝缘性能机理分析、故障预测与健康管理。E-mail: liukai@swjtu.edu.cn
引用本文:   
刘凯, 张鹏鹏, 高波, 杨雁, 吴广宁. ZnO@PS粒子分散特性及改性乙丙橡胶绝缘性能研究[J]. 电工技术学报, 2023, 38(8): 2265-2276. Liu Kai, Zhang Pengpeng, Gao Bo, Yang Yan, Wu Guangning. Research on the Dispersion Characteristics of ZnO@PS Particles and the Insulation Characteristics of Modified Ethylene Propylene Rubber. Transactions of China Electrotechnical Society, 2023, 38(8): 2265-2276.
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