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Self-Healing Property of One-Component Photosensitive Microcapsule/Nano-SiO2/Epoxy Composite Dielectric |
Liang Chen, Sima Wenxia, Sun Potao, Liu Fengqi, Shao Qianqiu |
State Key Laboratory of Power Transmission Equipment & System Security and New Technology Chongqing University Chongqing 400044 China |
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Abstract The solid insulating materials represented by epoxy resin inevitably generate local cracks under long-term electrical/mechanical stress, which seriously affects their service life. In this paper, a novel epoxy insulating composite with one-component UV-photosensitive microcapsules is proposed. When the crack is generated and the microcapsule is broken, the damage channel is filled with the photosensitive healing agent and cured by UV excitation. Meanwhile, nano-SiO2 is introduced into the epoxy matrix as an ultraviolet reflecting agent to protect the healing agent in the microcapsule from the premature polymerization. Properties of microcapsules and composites are tested by optical microscope (OM), scanning electron microscope (SEM), infrared spectrometer, thermogravimetric analyzer and dielectric spectrum analyzer. The results show that the microcapsules are compact and uniform, and have good heat resistance. In addition, the SiO2 composite matrix has significant UV-shielding effect, which ensures the reactivity of the healing agent from the capsule core. And the composite has an excellent effect on the healing of micro-crack damage while maintaining good intrinsic properties of epoxy resin.
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Received: 10 July 2020
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