环保绝缘气体C<sub>4</sub>F<sub>7</sub>N研究及应用进展Ⅱ：相容性、安全性及设备研发

doi:10.19595/j.cnki.1000-6753.tces.210057

Abstract
Figure/Table
References
Related Citation (4)

Download: PDF (4911 KB) HTML (1 KB)
Export: BibTeX | EndNote (RIS)

Abstract The development of new generation eco-friendly gas insulating equipment to promote the green upgrade of power transmission and distribution equipment manufacturing industry meets the strategic needs of building a clean and low-carbon energy system. In this paper, based on the Review Part I, we focused on the research progress of perfluoroisobutyronitrile (C₄F₇N) performance at application level. Firstly, current studies on the compatibility of C₄F₇N with metal and non-metallic materials were summarized. The gas-solid interface stability of C₄F₇N was also evaluated. Secondly, the biological safety parameters of C₄F₇N and its gas mixture were analyzed, and relevant targeted application protection suggestions were proposed. Finally, the development of C₄F₇N based gas insulated power transmission and distribution equipment as well as their application status were reviewed. The main problems and future development trends of eco-friendly gas insulating medium were also prospected.

Key words： Eco-friendly gas C₄F₇N gas mixture material compatibility biological safety equipment development

Received: 14 January 2021

PACS:

TM835

	Service

	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	Li Yi
	Zhang Xiaoxing
	Fu Mingli
	Xiao Song
	Tang Ju
	Tian Shuangshuang

Cite this article:

Li Yi,Zhang Xiaoxing,Fu Mingli等. Research and Application Progress of Eco-Friendly Gas Insulating Medium C₄F₇N, Part II: Material Compatibility, Safety and Equipment Development[J]. Transactions of China Electrotechnical Society, 2021, 36(21): 4567-4579.

URL:

https://dgjsxb.ces-transaction.com/EN/10.19595/j.cnki.1000-6753.tces.210057 OR https://dgjsxb.ces-transaction.com/EN/Y2021/V36/I21/4567

[1] 唐炬, 杨东, 曾福平, 等. 基于分解组分分析的SF₆设备绝缘故障诊断方法与技术的研究现状[J]. 电工技术学报, 2016, 31(20): 41-54.
Tang Ju, Yang Dong, Zeng Fuping, et al.Research status of SF₆ insulation equipment fault diagnosis method and technology based on decomposed components analysis[J]. Transactions of China Electrotechnical Society, 2016, 31(20): 41-54.
[2] Fu Yuwei, Yang Aijun, Wang Xiaohua, et al[J]. Journal of Physics D: Applied Physics, 2016, 49(38): 385203.
[3] Fang Xuekun, Hu Xia, Janssens-Maenhout G, et al.Sulfur hexafluoride (SF₆) emission estimates for China: an inventory for 1990-2010 and a projection to 2020[J]. Environmental Science & Technology, 2013, 47(8): 3848-3855.
[4] Rabie M, Franck C M.Assessment of eco-friendly gases fheoretical study of the neutral decomposition of SF₆ in the presence of H₂O and O₂ in discharges in power equipmentor electrical insulation to replace the most potent industrial greenhouse gas SF₆[J]. Environmental Science & Technology, 2018, 52(2): 369-380.
[5] Zhang Boya, Xiong Jiayu, Chen Li, et al.Fundamental physicochemical properties of SF₆-alternative gases: a review of recent progress[J]. Journal of Physics D: Applied Physics, 2020, 53(17): 173001.
[6] Kessler F, Sarfert-Gast W, Ise M, et al.Interaction of low global warming potential gaseous dielectrics with materials of gas-insulated systems[C]//Proceedings 20th International Symposium High Voltage Engineering, Buenos Aire, Argentina, 2017.
[7] Zhang Xiaoxing, Li Yi, Chen Dachang, et al.Dissociative adsorption of environment-friendly insulating medium C₃F₇CN on Cu (111) and Al (111) surface: a theoretical evaluation[J]. Applied Surface Science, 2018, 434: 549-560.
[8] Li Yi, Zhang Xiaoxing, Xiao Song, et al.Insight into the compatibility between C₄F₇N and silver: experiment and theory[J]. Journal of Physics and Chemistry of Solids, 2019, 126: 105-111.
[9] Xiong Jiayu, Zhang Boya, Zhang Ziyue, et al.The adsorption properties of environmentally friendly insulation gas C₄F₇N on Zn (0 0 0 1) and ZnO (1 0 1 0) surfaces: a first-principles study[J]. Applied Surface Science, 2020, 509: 144854.
[10] Li Yi, Zhang Xiaoxing, Zhang Ji, et al.Thermal compatibility between perfluoroisobutyronitrile-CO₂ gas mixture with copper and aluminum switchgear[J]. IEEE Access, 2019, 7: 19792-19800.
[11] Li Yi, Zhang Xiaoxing, Chen Qichen, et al.Study on the thermal interaction mechanism between C₄F₇N-N₂ and copper, aluminum[J]. Corrosion Science, 2019, 153: 32-46.
[12] Kessler F, Sarfert-Gast W, Kuhlmann L, et al.Compatibility of a gaseous dielectric with Al, Ag and Cu and gas-phase synthesis of a new N-Acylamidine copper complex[J]. European Journal of Inorganic Chemistry, 2020, 20: 1989-1994.
[13] 郑哲宇, 李涵, 周文俊, 等. 环保绝缘气体C₃F₇CN与密封材料三元乙丙橡胶的相容性研究[J]. 高电压技术, 2020, 46(1): 335-341.
Zheng Zheyu, Li Han, Zhou Wenjun, et al.Compatibility of eco-friendly insulating medium C₃F₇CN and sealing material EPDM[J]. High Voltage Engineering, 2020, 46(1): 335-341.
[14] Li Yi, Zhang Xiaoxing, Li Yalong, et al.Interaction mechanism between the C₄F₇N-CO₂ gas mixture and the EPDM seal ring[J]. ACS Omega, 2020, 5(11): 5911-5920.
[15] 张亚茹, 刘静, 黄青丹, 等. 绝缘环保气体全氟异丁腈和二氧化碳对三元乙丙橡胶和丁腈橡胶耐老化性能的影响[J]. 橡胶工业, 2020, 67(3): 177-180.
Zhang Yaru, Liujing, Huang Danqing, et al.Effect of insulating and enviromental gas C₄F₇N and CO₂ on aging resistance of EPDM and NBR[J]. China Rubber Industry, 2020, 67(3): 177-180.
[16] Kieffel Y.Characteristics of g3-an alternative to SF₆[C]//2016 IEEE International Conference on Dielectrics (ICD), Montpellier, 2016, 2: 880-884.
[17] Yuan Ruijun, Li Han, Zhou Wenjun, et al.Study of Compatibility between epoxy resin and C₄F₇N/CO₂ based on thermal ageing[J]. IEEE Access, 2020, 8: 119544-119553.
[18] 李涵, 郑哲宇, 袁瑞君, 等. 气体绝缘设备中气固材料的相容性[J]. 电工技术学报, 2020, 35(11): 2460-2468.
Li Han, Zheng Zheyu, Yuan Ruijun, et al.Compatibility between gas and solid materials in gas insulated equipment[J]. Transactions of China Electrotechnical Society, 2020, 35(11): 2460-2468.
[19] Wang Cong, Ai Xin, Zhang Ying, et al.Decomposition characteristics and marker products of C₃F₇CN/EP insulation system with long-term surface discharge[J]. Engineering Failure Analysis, 2020, 116: 104719.
[20] Zhang Boya, Zhang Ziyue, Li Xingwen, et al.The compatibility between environmentally friendly insulation gas C₄F₇N and α-Al₂O₃ (0001) surface: Theoretical and experimental insights[J]. Applied Surface Science, 2021, 536: 147839.
[21] Xiao Song, Chen Dachang, Tang Ju, et al.Adsorption behavior of γ-Al₂O₃ toward heptafluoroisobutyronitrile and its decompositions: theoretical and experimental insights[J]. IEEE Access, 2020, 8: 36741-36748.
[22] 肖淞, 张季, 张晓星, 等. 活性氧化铝对新型环保绝缘气体C₃F₇CN/N₂及其放电分解产物吸附特性[J]. 高电压技术, 2018, 44(10): 3135-3140.
Xiao Song, Zhang Ji, Zhang Xiaoxing, et al.Adsorption characteristics of γ-A1₂O₃ for the environment-friendly insulating medium C₃F₇CN/N₂ and its decomposition product[J]. High Voltage Engineering, 2018, 44(10): 3135-3140.
[23] 侯华, 颜湘莲, 余小娟, 等. 分子筛吸附C₄F₇N/CO₂混合绝缘气体及其分解产物的理论研究[J]. 高电压技术, 2019, 45(4): 1040-1047.
Hou Hua, Yan Xianglian, Yu Xiaojuan, et al.Theoretical investigation on the adsorption of C₄F₇N/CO₂ dielectric gas and decomposition products in zeolite[J]. High Voltage Engineering, 2019, 45(4): 1040-1047.
[24] 赵明月, 韩冬, 周朕蕊, 等. 活性氧化铝和分子筛对C₄F₇N/CO₂及其过热分解产物的吸附特性[J]. 电工技术学报, 2020, 35(1): 88-96.
Zhao Mingyue, Han Dong, Zhou Zhenrui, et al.Adsorption characteristics of activated aluminaand molecular sieves for C₃F₇CN/CO₂ and its decomposition by-products of overheating fault[J]. Transactions of China Electrotechnical Society, 2020, 35(1): 88-96.
[25] Pohlink K, Meyer F, Kieffel Y, et al.Characteristics of Fluoronitrile/CO₂ mixture-an alternative to SF₆[C]//CIGRED1 Working Group Reports, Paris, France, 2016: 204.
[26] 李祎, 张晓星, 陈琪, 等. 气体绝缘介质C₄F₇N的急性吸入毒性试验[J]. 高电压技术, 2019, 45(1): 109-116.
Li Yi, Zhang Xiaoxing, Chen Qi, et al.Acute inhalation toxicity studies of gas insulating medium C₄F₇N[J]. High Voltage Engineering, 2019, 45(1): 109-116.
[27] Li Yi, Zhang Xiaoxing, Zhang Ji, et al.Assessment on the toxicity and application risk of C₄F₇N: a new SF₆ alternative gas[J]. Journal of Hazardous Materials, 2019, 368: 653-660.
[28] Zhang Xiaoxing, Ye Fanchao, Li Yi, et al.Acute toxicity and health effect of perfluoroisobutyronitrile on mice: a promising substitute gas-insulating medium to SF₆[J]. Journal of Environmental Science and Health, Part A, 2020: 1-13.
[29] Muijser H, van Triel J J, Duistermaat E, et al. Acute toxicity of high concentrations of carbon dioxide in rats[J]. Regulatory Toxicology and Pharmacology, 2014, 69(2): 201-206.
[30] Düzkaya H, Tezcan S S, Acartürk A, et al.Environmental and physiochemical properties of gaseous dielectrics alternatives to SF₆[J]. El-Cezeri Journal of Science and Engineering, 2020, 7(3): 1460-1470.
[31] Levin B C, Paabo M, Gurman J L, et al.Effects of exposure to single or multiple combinations of the predominant toxic gases and low oxygen atmospheres produced in fires[J]. Toxicological Sciences, 1987, 9(2): 236-250.
[32] Beroual A, Haddad A M.Recent advances in the quest for a new insulation gas with a low impact on the environment to replace sulfur hexafluoride (SF₆) gas in high-voltage power network applications[J]. Energies, 2017, 10(8): 1216.
[33] Preve C, Maladen R, Piccoz D, Validation method and comparison of SF₆ alternative gases[C]//23rd Internationl Conference on Elecricity Distribution, Paris, France, 2016: 493.
[34] Dincer M S, Dincer S, Duzkaya H, et al.DFT Analysis of neutral decomposition by-products in SF₆-CO₂ mixture[C]//2020 IEEE International Conference on Environment and Electrical Engineering and IEEE Industrial and Commercial Power Systems Europe (EEEIC/I&CPS Europe), Madrid, 2020: 1-6.
[35] Romero A, Rácz L, Mátrai A, et al.A review of sulfur-hexafluoride reduction by dielectric coatings and alternative gases[C]// 6th International Youth Conference on Energy (IYCE), Budapest, 2017: 1-5.
[36] Tu Youping, Chen Geng, Wang Cong, et al.Feasibility of C₃F₇CN/CO₂ gas mixtures in high-voltage DC GIL: a review on recent advances[J]. High Voltage, 2020, 5(4): 377-386.
[37] Kieffel Y, Irwin T, Ponchon P, et al.Green gas to replace SF₆ in electrical grids[J]. IEEE Power and Energy Magazine, 2016, 14(2): 32-39.
[38] Gautschi D, Ficheux A, Walter M, et al.Application of a fluoronitrile gas in GIS and GIL as an environmental friendly alternative to SF₆[C]// CIGRE Working Group B3 Reports, Paris, France, 2016: 106.
[39] Meyer F, Kieffel Y.Application of Fluoronitrile/ CO₂/O₂ mixtures in high voltage products to lower the environmental footprint[C]// CIGRE D1 Working Group Reports, Paris, France, 2018: 201.
[40] Lindner C, Gautsch D.Application of a fluoronitrile gas in a 123kV GIS pilot substation[C]//CIGRE B3 Working Group Reports, Paris, 2018: 146.
[41] Gautschi D, Luescher R, Kieffel Y, Comparative life cycle assessment of an environmentally friendly 145 kV gas insulated substation[C]//CIGRE C3 Working Group Reports, Paris, France, 2018: 302.
[42] 中国电力科学研究院. 国内首台全氟异丁腈(C4F7N)气体环网柜样机研制成功[EB/OL].(2019-01-14) [2021-03-15]. http://m.chinasmartgrid.com.cn/ mnews/20190114/631665.shtml
[43] 中国电工技术学会. “新型环保气体绝缘关键技术研究及工程应用”项目通过科技成果鉴定[EB/OL]. (2020-01-14) [2021-03-15]. http://www.ces.org.cn/ xhtml/report/20011114-1.htm
[44] 高克利, 颜湘莲, 刘焱, 等. 环保气体绝缘管道技术研究进展[J]. 电工技术学报, 2020, 35(1): 3-20.
Gao Keli, Yan Xianglian, Liu Yan, et al.Progress of technology for environment-friendly gas insulated transmission line[J]. Transactions of China Electrotechnical Society, 2020, 35(1): 3-20.
[45] 高克利, 颜湘莲, 王浩, 等. 环保型气体绝缘输电线路(GIL) 技术发展[J]. 高电压技术, 2018, 44(10): 3105-3113.
Gao Keli, Yan Xianglian, Wang Hao, et al.Progress in environment-friendly gas-insulated transmission line (GIL)[J]. High Voltage Engineering, 2018, 44(10): 3105-3113.
[46] Zhang Yin, Zhang Xiaoxing, Liu Chang, et al.Ultraviolet spectral analysis and quantitative detection of heptafluoroisobutyronitrile(C₄F₇N) in a C₄F₇N-carbon dioxide (CO₂) gas mixture[J]. Applied Spectroscopy, 2019, 73(8): 917-926.
[47] 张晓星, 张引, 傅明利, 等. 基于紫外光谱的C₄F₇N/CO₂混合气体混合比检测[J]. 高电压技术, 2019, 45(4): 1034-1039.
Zhang Xiaoxing, Zhang Yin, Fu Mingli, et al.Mixing ratio detection for C₄F₇N/CO₂ mixed gas based on ultraviolet spectroscopy[J]. High Voltage Engineering, 2019, 45(4): 1034-1039.
[48] Zhang Yin, Zhang Xiaoxing, Liu Chang, et al.Research on C₄F₇N gas mixture detection based on infrared spectroscopy[J]. Sensors and Actuators A: Physical, 2019, 294: 126-132.
[49] Zhang Xiaoxing, Zhang Yin, Huang Yi, et al.Detection of decomposition products of C₄F₇N-CO₂ gas mixture based on infrared spectroscopy[J]. Vibrational Spectroscopy, 2020, 110: 103114.
[50] Zhang Xiaoxing, Zhang Yin, Zhou Siyuan, et al.The detection and quantification of heptafluoroiso-butyronitrile (C₄F₇N) and its decomposition products by infrared spectroscopy and chemometrics[J]. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2020, 233: 118161.