电极材料对低密度聚乙烯中空间电荷的影响

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摘要用电声脉冲法(PEA)测量了不同电极材料对低密度聚乙烯(LDPE)中空间电荷的影响。电极材料为常见的金属, 如:铝、含铅黄铜、含锌黄铜和紫铜。实验发现不同电极材料均有空穴和电子注入;并且在实验条件下电极功函数越高越容易注入空穴, 功函数越低越容易注入电子;铝(+)/紫铜(-)电极系统能有效减少聚乙烯中的空间电荷注入, 进而抑制因空间电荷聚集引起的局部场强过高。

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	陈少卿
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关键词 ：电极材料, 低密度聚乙烯, 空间电荷

Abstract：The effect of electrode on space charge in low-density polyethylene is investigated using the pulsed electro-acoustic (PEA) method. Commercial electrode materials are selected, for example, aluminum (Al), brass doped plumbum(Pb), brass doped zinc(Zn) and pure copper. The result shows that both hole and electron injecting from the electrodes into LDPE occurs; the higher work function of the electrode material, the more difficultly electron injecting; the lower work function of the electrode material, the more easily hole injecting; the Al(+)/ pure copper (-) electrode system can effectively suppress space charge injection, and thus the increment of local field due to space charge is reduced.

Key words： Electrode material low-density polyethylene space charge

收稿日期: 2009-07-27 出版日期: 2014-03-20

PACS:

TM206

基金资助:电力设备电气绝缘国家重点实验室中青年基础研究创新基金资助课题。

作者简介: 陈少卿男, 1983年生, 博士研究生, 主要研究方向为聚合物中空间电荷问题。郑明波男, 1986年生, 硕士研究生, 主要研究方向为聚合物中空间电荷问题。

引用本文:

陈少卿, 郑明波, 王霞, 彭宗仁. 电极材料对低密度聚乙烯中空间电荷的影响[J]. 电工技术学报, 2012, 27(5): 105-108. Chen Shaoqing, Zheng Mingbo, Wang Xia, Peng Zongren. Effects of Electrode Materials on Space Charge in Low-Density Polyethylene. Transactions of China Electrotechnical Society, 2012, 27(5): 105-108.

链接本文:

http://dgjsxb.ces-transaction.com/CN/Y2012/V27/I5/105

[1] 方亮, 付海金, 屠德民, 等. 等离子表面处理聚乙烯中空间电荷分布[J]. 中国电机工程学报, 2003, 23(8): 151-154.
Fang Liang, Fu Haijin, Tu Demin, et al. Space charge distribution of polyethylene after surface treatment by plasma[J]. Proceedings of the CSEE, 2003, 23(8): 151-154.
[2] 党智敏, 亢婕, 屠德民. EAA 改性XLPE 中空间电荷和电树、水树的关系[J]. 中国电机工程学报, 2001, 21(7): 5-8.
Dang Zhimin, Kang Jie, Tu Demin. Relationships of space chage accumulation with electrical and water treeing in XLPE modified by EAA[J]. Proceedings of the CSEE, 2001, 21(7): 5-8.
[3] Tanaka T. Charge transfer and tree initiation in polyethylene subject to AC voltage stress[J]. IEEE Transactions on EI, 1992, 27(3): 424-431.
[4] Abou-dakka M, Bulinski A, Bamji S. Space charge development and breakdown in XLPE under DC field[J]. IEEE Transactions on Dielectrics and Electrical Insulation, 2004, 11(1): 41-48.
[5] Kaneko K, Semi H, Mizutani T, et al. Charge transport and space charge formation in low density polyethylene[C]. Proceedings of the 6th ICPADM, Xi’an, China, 2000: 71-74.
[6] Tanaka Y, Chen G, Zhao Y, et al. Effect of additives on morphologyand space charge accumulation in low density polyethylene [J]. IEEE Transactions on Dielectrics and Electrical Insulation, 2003, 10(1): 148-154.
[7] 尹毅, 肖登明, 屠德民. 空间电荷在评估绝缘聚合物电老化程度中的应用[J]. 中国电机工程学报, 2002, 22(1): 43-48.
Yin Yi, Xiao Dengming, Tu Demin. Application of space charge in valuing the electric aging degree of insulating polymer[J]. Proceedings of the CSEE, 2002, 22(1): 43-48.
[8] 王霞, 吴超一, 何华琴, 等. 茂金属聚乙烯改性低密度聚乙烯中空间电荷机理的研究[J]. 中国电机工程学报, 2006, 26(7): 158-162.
Wang Xia, Wu Chaoyi, He Huaqin, et al. Study on mechanism of space charge in low density polyethylene modified metallocene catalyzed polyethylene[J]. Proceedings of the CSEE, 2006, 26(7): 158-162.
[9] Chen G, Tay T Y G, Davies A E, et al.Electrodes and charge injection in low-density polyethylene using the pulsed electroacoustic technique[J]. IEEE Transactions on Dielectrics and Electrical Insulation, 2001, 8(6): 867-873.