六氟化硫绝缘替代气体的构效关系与分子设计技术现状及发展

doi:10.19595/j.cnki.1000-6753.tces.190994

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Abstract Since SF₆ is the most potent greenhouse gas with the highest global warming potential, the search for a viable alternative is a world-widely hot topic with considerable challenges. Developments of structure-activity relationship and molecular design on the replacement dielectric gases for SF₆ were reviewed to breakthrough the bottleneck of both experimental and theoretical studies. Various models to predict the dielectric strengths of arbitrary insulation gases were detailed in terms of idea, methodology, and limitations. New protocols for the molecular design of the novel alternative gases were presented on the basis of the a priori theoretical models and quantum chemical calculations. The present review sheds new lights on the rational molecular design of new chemistries and will inspire experimental synthesis and field tests on the environmentally sustainable dielectric gases.

Key words： Sulfur hexafluoride replacement dielectric gas structure-activity relationship model molecular design quantum chemistry

Received: 11 July 2018 Published: 17 January 2020

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TM213

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	Wang Baoshan
	Yu Xiaojuan
	Hou Hua
	Zhou Wenjun
	Luo Yunbai

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Wang Baoshan,Yu Xiaojuan,Hou Hua等. Review on the Developments of Structure-Activity Relationship and Molecular Design of the Replacement Dielectric Gases for SF₆[J]. Transactions of China Electrotechnical Society, 2020, 35(1): 21-33.

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https://dgjsxb.ces-transaction.com/EN/10.19595/j.cnki.1000-6753.tces.190994 OR https://dgjsxb.ces-transaction.com/EN/Y2020/V35/I1/21

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