Research and Application Progress of Eco-Friendly Gas Insulating Medium C4F7N, Part II: Material Compatibility, Safety and Equipment Development
Li Yi1, Zhang Xiaoxing2, Fu Mingli3, Xiao Song1, Tang Ju2, Tian Shuangshuang2
1. School of Electrical Engineering and Automation Wuhan University Wuhan 430072 China; 2. Hubei Engineering Research Center for Safety Monitoring of New Energy and Power Grid Equipment Hubei University of Technology Wuhan 400068 China; 3. Electric Power Research Institute China Southern Power Grid Guangzhou 510080 China
Abstract:The development of new generation eco-friendly gas insulating equipment to promote the green upgrade of power transmission and distribution equipment manufacturing industry meets the strategic needs of building a clean and low-carbon energy system. In this paper, based on the Review Part I, we focused on the research progress of perfluoroisobutyronitrile (C4F7N) performance at application level. Firstly, current studies on the compatibility of C4F7N with metal and non-metallic materials were summarized. The gas-solid interface stability of C4F7N was also evaluated. Secondly, the biological safety parameters of C4F7N and its gas mixture were analyzed, and relevant targeted application protection suggestions were proposed. Finally, the development of C4F7N based gas insulated power transmission and distribution equipment as well as their application status were reviewed. The main problems and future development trends of eco-friendly gas insulating medium were also prospected.
李祎, 张晓星, 傅明利, 肖淞, 唐炬, 田双双. 环保绝缘气体C4F7N研究及应用进展Ⅱ:相容性、安全性及设备研发[J]. 电工技术学报, 2021, 36(21): 4567-4579.
Li Yi, Zhang Xiaoxing, Fu Mingli, Xiao Song, Tang Ju, Tian Shuangshuang. Research and Application Progress of Eco-Friendly Gas Insulating Medium C4F7N, Part II: Material Compatibility, Safety and Equipment Development. Transactions of China Electrotechnical Society, 2021, 36(21): 4567-4579.
[1] 唐炬, 杨东, 曾福平, 等. 基于分解组分分析的SF6设备绝缘故障诊断方法与技术的研究现状[J]. 电工技术学报, 2016, 31(20): 41-54. Tang Ju, Yang Dong, Zeng Fuping, et al.Research status of SF6 insulation equipment fault diagnosis method and technology based on decomposed components analysis[J]. Transactions of China Electrotechnical Society, 2016, 31(20): 41-54. [2] Fu Yuwei, Yang Aijun, Wang Xiaohua, et al[J]. Journal of Physics D: Applied Physics, 2016, 49(38): 385203. [3] Fang Xuekun, Hu Xia, Janssens-Maenhout G, et al.Sulfur hexafluoride (SF6) emission estimates for China: an inventory for 1990-2010 and a projection to 2020[J]. Environmental Science & Technology, 2013, 47(8): 3848-3855. [4] Rabie M, Franck C M.Assessment of eco-friendly gases fheoretical study of the neutral decomposition of SF6 in the presence of H2O and O2 in discharges in power equipmentor electrical insulation to replace the most potent industrial greenhouse gas SF6[J]. Environmental Science & Technology, 2018, 52(2): 369-380. [5] Zhang Boya, Xiong Jiayu, Chen Li, et al.Fundamental physicochemical properties of SF6-alternative gases: a review of recent progress[J]. Journal of Physics D: Applied Physics, 2020, 53(17): 173001. [6] Kessler F, Sarfert-Gast W, Ise M, et al.Interaction of low global warming potential gaseous dielectrics with materials of gas-insulated systems[C]//Proceedings 20th International Symposium High Voltage Engineering, Buenos Aire, Argentina, 2017. [7] Zhang Xiaoxing, Li Yi, Chen Dachang, et al.Dissociative adsorption of environment-friendly insulating medium C3F7CN on Cu (111) and Al (111) surface: a theoretical evaluation[J]. Applied Surface Science, 2018, 434: 549-560. [8] Li Yi, Zhang Xiaoxing, Xiao Song, et al.Insight into the compatibility between C4F7N and silver: experiment and theory[J]. Journal of Physics and Chemistry of Solids, 2019, 126: 105-111. [9] Xiong Jiayu, Zhang Boya, Zhang Ziyue, et al.The adsorption properties of environmentally friendly insulation gas C4F7N on Zn (0 0 0 1) and ZnO (1 0 1 0) surfaces: a first-principles study[J]. Applied Surface Science, 2020, 509: 144854. [10] Li Yi, Zhang Xiaoxing, Zhang Ji, et al.Thermal compatibility between perfluoroisobutyronitrile-CO2 gas mixture with copper and aluminum switchgear[J]. IEEE Access, 2019, 7: 19792-19800. [11] Li Yi, Zhang Xiaoxing, Chen Qichen, et al.Study on the thermal interaction mechanism between C4F7N-N2 and copper, aluminum[J]. Corrosion Science, 2019, 153: 32-46. [12] Kessler F, Sarfert-Gast W, Kuhlmann L, et al.Compatibility of a gaseous dielectric with Al, Ag and Cu and gas-phase synthesis of a new N-Acylamidine copper complex[J]. European Journal of Inorganic Chemistry, 2020, 20: 1989-1994. [13] 郑哲宇, 李涵, 周文俊, 等. 环保绝缘气体C3F7CN与密封材料三元乙丙橡胶的相容性研究[J]. 高电压技术, 2020, 46(1): 335-341. Zheng Zheyu, Li Han, Zhou Wenjun, et al.Compatibility of eco-friendly insulating medium C3F7CN and sealing material EPDM[J]. High Voltage Engineering, 2020, 46(1): 335-341. [14] Li Yi, Zhang Xiaoxing, Li Yalong, et al.Interaction mechanism between the C4F7N-CO2 gas mixture and the EPDM seal ring[J]. ACS Omega, 2020, 5(11): 5911-5920. [15] 张亚茹, 刘静, 黄青丹, 等. 绝缘环保气体全氟异丁腈和二氧化碳对三元乙丙橡胶和丁腈橡胶耐老化性能的影响[J]. 橡胶工业, 2020, 67(3): 177-180. Zhang Yaru, Liujing, Huang Danqing, et al.Effect of insulating and enviromental gas C4F7N and CO2 on aging resistance of EPDM and NBR[J]. China Rubber Industry, 2020, 67(3): 177-180. [16] Kieffel Y.Characteristics of g3-an alternative to SF6[C]//2016 IEEE International Conference on Dielectrics (ICD), Montpellier, 2016, 2: 880-884. [17] Yuan Ruijun, Li Han, Zhou Wenjun, et al.Study of Compatibility between epoxy resin and C4F7N/CO2 based on thermal ageing[J]. IEEE Access, 2020, 8: 119544-119553. [18] 李涵, 郑哲宇, 袁瑞君, 等. 气体绝缘设备中气固材料的相容性[J]. 电工技术学报, 2020, 35(11): 2460-2468. Li Han, Zheng Zheyu, Yuan Ruijun, et al.Compatibility between gas and solid materials in gas insulated equipment[J]. Transactions of China Electrotechnical Society, 2020, 35(11): 2460-2468. [19] Wang Cong, Ai Xin, Zhang Ying, et al.Decomposition characteristics and marker products of C3F7CN/EP insulation system with long-term surface discharge[J]. Engineering Failure Analysis, 2020, 116: 104719. [20] Zhang Boya, Zhang Ziyue, Li Xingwen, et al.The compatibility between environmentally friendly insulation gas C4F7N and α-Al2O3 (0001) surface: Theoretical and experimental insights[J]. Applied Surface Science, 2021, 536: 147839. [21] Xiao Song, Chen Dachang, Tang Ju, et al.Adsorption behavior of γ-Al2O3 toward heptafluoroisobutyronitrile and its decompositions: theoretical and experimental insights[J]. IEEE Access, 2020, 8: 36741-36748. [22] 肖淞, 张季, 张晓星, 等. 活性氧化铝对新型环保绝缘气体C3F7CN/N2及其放电分解产物吸附特性[J]. 高电压技术, 2018, 44(10): 3135-3140. Xiao Song, Zhang Ji, Zhang Xiaoxing, et al.Adsorption characteristics of γ-A12O3 for the environment-friendly insulating medium C3F7CN/N2 and its decomposition product[J]. High Voltage Engineering, 2018, 44(10): 3135-3140. [23] 侯华, 颜湘莲, 余小娟, 等. 分子筛吸附C4F7N/CO2混合绝缘气体及其分解产物的理论研究[J]. 高电压技术, 2019, 45(4): 1040-1047. Hou Hua, Yan Xianglian, Yu Xiaojuan, et al.Theoretical investigation on the adsorption of C4F7N/CO2 dielectric gas and decomposition products in zeolite[J]. High Voltage Engineering, 2019, 45(4): 1040-1047. [24] 赵明月, 韩冬, 周朕蕊, 等. 活性氧化铝和分子筛对C4F7N/CO2及其过热分解产物的吸附特性[J]. 电工技术学报, 2020, 35(1): 88-96. Zhao Mingyue, Han Dong, Zhou Zhenrui, et al.Adsorption characteristics of activated aluminaand molecular sieves for C3F7CN/CO2 and its decomposition by-products of overheating fault[J]. Transactions of China Electrotechnical Society, 2020, 35(1): 88-96. [25] Pohlink K, Meyer F, Kieffel Y, et al.Characteristics of Fluoronitrile/CO2 mixture-an alternative to SF6[C]//CIGRED1 Working Group Reports, Paris, France, 2016: 204. [26] 李祎, 张晓星, 陈琪, 等. 气体绝缘介质C4F7N的急性吸入毒性试验[J]. 高电压技术, 2019, 45(1): 109-116. Li Yi, Zhang Xiaoxing, Chen Qi, et al.Acute inhalation toxicity studies of gas insulating medium C4F7N[J]. High Voltage Engineering, 2019, 45(1): 109-116. [27] Li Yi, Zhang Xiaoxing, Zhang Ji, et al.Assessment on the toxicity and application risk of C4F7N: a new SF6 alternative gas[J]. Journal of Hazardous Materials, 2019, 368: 653-660. [28] Zhang Xiaoxing, Ye Fanchao, Li Yi, et al.Acute toxicity and health effect of perfluoroisobutyronitrile on mice: a promising substitute gas-insulating medium to SF6[J]. Journal of Environmental Science and Health, Part A, 2020: 1-13. [29] Muijser H, van Triel J J, Duistermaat E, et al. Acute toxicity of high concentrations of carbon dioxide in rats[J]. Regulatory Toxicology and Pharmacology, 2014, 69(2): 201-206. [30] Düzkaya H, Tezcan S S, Acartürk A, et al.Environmental and physiochemical properties of gaseous dielectrics alternatives to SF6[J]. El-Cezeri Journal of Science and Engineering, 2020, 7(3): 1460-1470. [31] Levin B C, Paabo M, Gurman J L, et al.Effects of exposure to single or multiple combinations of the predominant toxic gases and low oxygen atmospheres produced in fires[J]. Toxicological Sciences, 1987, 9(2): 236-250. [32] Beroual A, Haddad A M.Recent advances in the quest for a new insulation gas with a low impact on the environment to replace sulfur hexafluoride (SF6) gas in high-voltage power network applications[J]. Energies, 2017, 10(8): 1216. [33] Preve C, Maladen R, Piccoz D, Validation method and comparison of SF6 alternative gases[C]//23rd Internationl Conference on Elecricity Distribution, Paris, France, 2016: 493. [34] Dincer M S, Dincer S, Duzkaya H, et al.DFT Analysis of neutral decomposition by-products in SF6-CO2 mixture[C]//2020 IEEE International Conference on Environment and Electrical Engineering and IEEE Industrial and Commercial Power Systems Europe (EEEIC/I&CPS Europe), Madrid, 2020: 1-6. [35] Romero A, Rácz L, Mátrai A, et al.A review of sulfur-hexafluoride reduction by dielectric coatings and alternative gases[C]// 6th International Youth Conference on Energy (IYCE), Budapest, 2017: 1-5. [36] Tu Youping, Chen Geng, Wang Cong, et al.Feasibility of C3F7CN/CO2 gas mixtures in high-voltage DC GIL: a review on recent advances[J]. High Voltage, 2020, 5(4): 377-386. [37] Kieffel Y, Irwin T, Ponchon P, et al.Green gas to replace SF6 in electrical grids[J]. IEEE Power and Energy Magazine, 2016, 14(2): 32-39. [38] Gautschi D, Ficheux A, Walter M, et al.Application of a fluoronitrile gas in GIS and GIL as an environmental friendly alternative to SF6[C]// CIGRE Working Group B3 Reports, Paris, France, 2016: 106. [39] Meyer F, Kieffel Y.Application of Fluoronitrile/ CO2/O2 mixtures in high voltage products to lower the environmental footprint[C]// CIGRE D1 Working Group Reports, Paris, France, 2018: 201. [40] Lindner C, Gautsch D.Application of a fluoronitrile gas in a 123kV GIS pilot substation[C]//CIGRE B3 Working Group Reports, Paris, 2018: 146. [41] Gautschi D, Luescher R, Kieffel Y, Comparative life cycle assessment of an environmentally friendly 145 kV gas insulated substation[C]//CIGRE C3 Working Group Reports, Paris, France, 2018: 302. [42] 中国电力科学研究院. 国内首台全氟异丁腈(C4F7N)气体环网柜样机研制成功[EB/OL].(2019-01-14) [2021-03-15]. http://m.chinasmartgrid.com.cn/ mnews/20190114/631665.shtml [43] 中国电工技术学会. “新型环保气体绝缘关键技术研究及工程应用”项目通过科技成果鉴定[EB/OL]. (2020-01-14) [2021-03-15]. http://www.ces.org.cn/ xhtml/report/20011114-1.htm [44] 高克利, 颜湘莲, 刘焱, 等. 环保气体绝缘管道技术研究进展[J]. 电工技术学报, 2020, 35(1): 3-20. Gao Keli, Yan Xianglian, Liu Yan, et al.Progress of technology for environment-friendly gas insulated transmission line[J]. Transactions of China Electrotechnical Society, 2020, 35(1): 3-20. [45] 高克利, 颜湘莲, 王浩, 等. 环保型气体绝缘输电线路(GIL) 技术发展[J]. 高电压技术, 2018, 44(10): 3105-3113. Gao Keli, Yan Xianglian, Wang Hao, et al.Progress in environment-friendly gas-insulated transmission line (GIL)[J]. High Voltage Engineering, 2018, 44(10): 3105-3113. [46] Zhang Yin, Zhang Xiaoxing, Liu Chang, et al.Ultraviolet spectral analysis and quantitative detection of heptafluoroisobutyronitrile(C4F7N) in a C4F7N-carbon dioxide (CO2) gas mixture[J]. Applied Spectroscopy, 2019, 73(8): 917-926. [47] 张晓星, 张引, 傅明利, 等. 基于紫外光谱的C4F7N/CO2混合气体混合比检测[J]. 高电压技术, 2019, 45(4): 1034-1039. Zhang Xiaoxing, Zhang Yin, Fu Mingli, et al.Mixing ratio detection for C4F7N/CO2 mixed gas based on ultraviolet spectroscopy[J]. High Voltage Engineering, 2019, 45(4): 1034-1039. [48] Zhang Yin, Zhang Xiaoxing, Liu Chang, et al.Research on C4F7N gas mixture detection based on infrared spectroscopy[J]. Sensors and Actuators A: Physical, 2019, 294: 126-132. [49] Zhang Xiaoxing, Zhang Yin, Huang Yi, et al.Detection of decomposition products of C4F7N-CO2 gas mixture based on infrared spectroscopy[J]. Vibrational Spectroscopy, 2020, 110: 103114. [50] Zhang Xiaoxing, Zhang Yin, Zhou Siyuan, et al.The detection and quantification of heptafluoroiso-butyronitrile (C4F7N) and its decomposition products by infrared spectroscopy and chemometrics[J]. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2020, 233: 118161.