非平衡态等离子体的仿真研究现状与新进展

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摘要非热力学平衡态等离子体技术既是现代工业的关键技术之一,也是未来高科技的重要发展方向。通过仿真研究深入揭示此类等离子体的微观机理,阐明等离子体的宏观特性变化规律,对于提高科学认知水平并促进产业发展具有重要意义。传统的仿真研究主要集中于低气压条件下的非热力学平衡态等离子体,在大气压及更高气压条件下开展较少。本文主要针对高气压非热力学平衡态等离子体,对国内外仿真模型进行了综述。非热力学平衡态等离子体一般包括局部化学平衡和非化学平衡两种状态,前者中的粒子组分可由宏观的热力学统计原理计算得到,后者必需考察微观的物理和化学过程。针对局部化学平衡态等离子体,介绍了双温度条件下微观粒子组分和宏观物理特性分布规律的计算模型,重点讨论了基于质量作用定律、吉布斯自由焓最小化原理与化学动力学方法的粒子组分计算方法;针对非化学平衡态等离子体,介绍了基于漂移-扩散原理的流体模型和化学动力学模型,提出了全局模型与流体模型的联合仿真新方法。

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关键词 ：非热力学平衡, 局部化学平衡, 非化学平衡, 双温模型, 全局模型

Abstract：The non-equilibrium plasma technology is a key technology of the modern industry, and also an important high-tech development direction in near future. The microscopic mechanism underlying in such plasma, and its relationship to the macroscopic properties, need to be further unraveled. That is of great significance for improving the level of scientific understanding and to promote industrial development. Until now, much simulation research has focused on the low-pressure non-equilibrium plasma, but little for its atmospheric or even higher pressure counterparts. The numerical models of high-pressure non-equilibrium plasmas are reviewed in this paper. Non-equilibrium plasma normally has two states: local chemical equilibrium (LCE) state and non local chemical equilibrium (NLCE) state. The particle components in the former one can be obtained by using macroscopic thermodynamic statistical theory, but the latter one is more complicated, for the characteristic times of transport processes are comparable or less than the equilibration times of chemical reactions. Two-temperature models for the simulation of particle components and spatio-temporal resolved physical properties are discussed for non-equilibrium LCE-state plasmas, with emphasis on the methods based on mass action law, Gibbs free energy enthalpy principle and chemical kinetics. On the other hand, fluid model based on drift-diffusion equations and kinetic model are discussed for non-equilibrium NLCE-state plasmas, and a new simulation method by the combination of global model and fluid model is put forward.

Key words： Non thermal equilibrium local chemical equilibrium non local chemical equilibrium two-temperature model global model

收稿日期: 2012-09-20 出版日期: 2014-11-05

PACS:

TM5012

作者简介: 刘定新男，1982年生，博士，副教授，研究方向为低温等离子体理论与技术。

引用本文:

荣命哲, 刘定新, 李, 美, 王伟宗. 非平衡态等离子体的仿真研究现状与新进展[J]. 电工技术学报, 2014, 29(6): 271-282. Rong Mingzhe,Liu Dingxin,Li Mei,Wang Weizong. Research Status and New Progress on the Numerical Simulation of Non-Equilibrium Plasmas. Transactions of China Electrotechnical Society, 2014, 29(6): 271-282.

链接本文:

http://dgjsxb.ces-transaction.com/CN/Y2014/V29/I6/271

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